Conversion of C[triple bond]C to CO in alkynyl-metal complexes: oxidation of carbon chains capped by carbon-tricobalt clusters. 来自 国家科技图书文献中心 喜欢 0 阅读量: 25 作者:MI Bruce,PA Humphrey,NN Zaitseva,BK Nicholson,BW Skelton,AH White ...
The microwave spectra of fluorocyanobutadiyne, FC5N, in the ground, nu(sub 11) (skeletal bending) and 2nu(sub 11) states were observed with a source-modulated spectrometer. The FC5N molecule was generated in a free space absorption cell by a dc glow discharge in pentafluorobenzonitrile, C6F...
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Name an organic compound with a double bond. Write structural formulas for all of the possible isomers of n-hexyne that can be formed by moving the position of the triple bond. (a) What are nucleophile and electrophile? (b) Give three examples of each. ...
Matsuo R, Synthetic pyrethroids containing a C--C triple bond. Pestic Sci 52:21-28 (1998).Matsuo, N. Synthetic Pyrethroids Containing a C-C Triple Bond. Pestic. Sci. 1998, 52, 2-8.Matsuo N.Synthetic pyrethroids containing a C–C triple bond. Pesticide Science . 1998...
TiCl{sub 3}(DME){sub 1.5} (DME = 1,2-dimethoxyethane) and a Zn-Cu couple react with [PPN]{sub 2}[Fe{sub 3}(CO){sub 9}(CCO)] to give the new compound [PPN][Fe{sub 3}(CO){sub 9}(C{triple_bond}CH)] (1) (70% yield), a known compound [Fe{sub 3}(CO){sub 1...
13C-13C SSCC values across the triple bond in activated acetylenes are determined primarily by the -electronic properties of substituents. The enhanced sensitivity of1Jcc in acetylene derivatives to substituent effects also asserts their possible utility in estimating the electronegative properties of su...
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