Mechanism of benzene hydroxylation by high-valent bare Fe iv [double bond, length as m-dash]O 2+ : explicit electronic structure analysis The conversion of benzene to phenol by high-valent bare FeO2+ was comprehensively explored using a density functional theory method. The conductor-like scr....
A B-C Double Bond Unit Coordinated to Platinum: An Alkylideneboryl Ligand that Is Isoelectronic to Neutral Aminoborylene Ligands A B-C Double Bond Unit Coordinated to Platinum: An Alkylideneboryl Ligand that Is Isoelectronic to Neutral Aminoborylene Ligands... F Hupp,J Brand,H Braunschweig - ...
In a process for oxidizing an organic compound containing at least one C-C double bond, or a mixture of two or more thereof, which comprises the step (II) below:(II) reaction of the organic compound or the mixture of two or more thereof with a medium comprising molecular oxygen in the...
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The remaining 25% of mix-1 is represented by mesomeric R,S-1 which nominally plays a spectator role in both C-H and C[double bond, length as m-dash]C bond oxidation reactions. Overall, this mixture of iron complexes displays the same catalytic profile as its enantiopure components that ...
Why is the C=O double bond so much more polar than the C-O single bond?Question:Why is the C=O double bond so much more polar than the C-O single bond?PolarityPolarity is a measure of the unequal distribution of electrons between two atoms that results in a dipole. ...
In the reaction between (I) and (II) an initial reversible equilibrium involving a bis-ethylene adduct (III) is observed.doi:10.1002/chin.199048034CAYTON, R. H.CHACON, S. T.CHISHOLM, M. H.HUFFMAN, J. C.WILEY‐VCH Verlag GmbHChemInform...
Article 01 July 2024 Radical-triggered translocation of C–C double bond and functional group Article 09 September 2024 Copper-catalysed benzylic C–H coupling with alcohols via radical relay enabled by redox buffering Article 24 February 2020 Data...
C−S Bond Cleavage and C−C Coupling in Cyclopentadienylchromium Complexes To Give the First Dithiooxamide-Bridged and Doubly Dithiocarbamate-Bridged Double Cubanes: [Cp6Cr8S8{(C(S)NEt2)2}] and [Cplt.关键词: Chrom Clusterverbindungen Cubane S-Liganden DOI...