Catalytic hydrogenation of C{double bond, long}O and C{double bond, long}N bonds via heterolysis of H2 mediated by metal-sulfur bonds of rhodium and iridium thiolate complexesSakamoto, MayumiOhki, YasuhiroKehr, GeraldErker, GerhardTatsumi, Kazuyuki...
Compared to H2-assisted activation mode, the direct dissociation of CO2 into carbonyl (*CO) with a simplified reaction route is advantageous for CO2-related synthetic processes and catalyst upgrading, while the stable C = O double bond makes it very challenging. Herein, we construct a subna...
We first constructed and equilibrated the electrochemical Cu (100)/water interface with various reaction intermediates. The performed AIMD simulations of the as-constructed interface were used to obtain the temperature and potential energy profiles shown in Supplementary Fig.S1. Information on the calcula...
In a process for oxidizing an organic compound containing at least one C-C double bond, or a mixture of two or more thereof, which comprises the step (II) below:(II) reaction of the organic compound or the mixture of two or more thereof with a medium comprising molecular oxygen in the...
conjugated double bond 共轭双键conjugated lipid 结合脂质conjugated polyene 共轭聚烯conjugated polymers 共轭聚合物conjugated protein 结合蛋白质conjugated system 共轭系conjugation 共轭conjugation effect 共轭效应consecutive reaction 连锁反应conservative system 保守系consistency 稠度consistometer 稠度计consolute temperature ...
The remaining 25% of mix-1 is represented by mesomeric R,S-1 which nominally plays a spectator role in both C-H and C[double bond, length as m-dash]C bond oxidation reactions. Overall, this mixture of iron complexes displays the same catalytic profile as its enantiopure components that ...
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diarylcarbenium ions than propene; Le., the allylic trimethylsilyl group reduces the activation energy for electrophilic attack at the CC double bond by 18... G Hagen,H Mayr - 《Journal of the American Chemical Society》 被引量: 0发表: 1991年 Correction to Synthesis of Diaryl Ketones through...
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