论文信息: Direct C-C Double Bond Cleavage of Alkenes Enabled by Highly Dispersed Cobalt Catalyst and Hydroxylamine Wenxuan Xue, Yijie Jiang, Hongcheng Lu, Bo You, Xu Wang, andConghui Tang* Angew. Chem. Int. Ed.2023, 62, e202314364. 论文链接:https://onlinelibrary.wiley.com/doi/10.1002/ani...
Article 01 July 2024 Radical-triggered translocation of C–C double bond and functional group Article 09 September 2024 Copper-catalysed benzylic C–H coupling with alcohols via radical relay enabled by redox buffering Article 24 February 2020 Data...
16). As a result, C197 is potentially capable of forming hydrogen bonds with both H372 and a lower C436 (Fig. 3d). Fig. 3: Structure and mechanism of CalA3 KS domain. a Structure of KS dimer, shown in ribbon representation. b Close-up view of the disconnected, double open-ended ...
A B-C Double Bond Unit Coordinated to Platinum: An Alkylideneboryl Ligand that Is Isoelectronic to Neutral Aminoborylene Ligands... F Hupp,J Brand,H Braunschweig - 《Angewandte Chemie》 被引量: 0发表: 2014年 Reactions of 1,4- and 2,3-Diazadienes with Titanocene and Zirconocene Complexes...
The remaining 25% of mix-1 is represented by mesomeric R,S-1 which nominally plays a spectator role in both C-H and C[double bond, length as m-dash]C bond oxidation reactions. Overall, this mixture of iron complexes displays the same catalytic profile as its enantiopure components that ...
All ENEs require an additional cofactor (NADH or NADPH) for reducing the C=C double bond. To be able to use this cofactor in catalytic amounts, the oxidised cofactor has to be continuously reduced, this is called cofactor regeneration. The enzymes accept either or both NAD(P)H ...
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It is well documented that in addition to their ability to maintain the metal cluster framework intact during chemical reactions the dppm ligand in [Ru3(CO)10(μ-dppm)] (1) can also undergo C–H and P–C bond cleavage and M–H and M–C bond forming reactions to give many interesting ...
Pd(II)-catalyzed direct C5-arylation of azole-4-carboxylates through double C–H bond cleavage The first palladium-catalyzed direct C5-arylation of azole-4-carboxylates with simple unactivated arenes through double C–H bond cleavage is realized. Thi... Z Li,L Ma,J Xu,... - 《Chemical ...
In contrast to Ado∙, the putative thiyl radical in GREs can be much more easily regenerated by the product radical (cysteine S–H bond enthalpy, ∼87 kcal/mol; Rauk et al., 1998), removing the necessity for the migration mechanism. Significance Although it has long been known that ...