OzonolysisIron tetramesitylporphyrin complexesRuthenium porphyrin complexesAlkene epoxidationThe epoxidation of a number of cyclic and linear terminal alkenes by an O2–O3 mixture at room temperatures catalysed by Fe(TMP)Cl is reported. It appears that the alkene forms a primary ozonide which rearranges...
select article Interrupted Dance of Five Heteroatoms: Reinventing Ozonolysis to Make Geminal Alkoxyhydroperoxides from C N Bonds Research articleAbstract only Interrupted Dance of Five Heteroatoms: Reinventing Ozonolysis to Make Geminal Alkoxyhydroperoxides from C N Bonds Ivan A. Yaremenko, Dmitri I. Fo...
ChemInform Abstract: Kinetic Study of the Epoxidation of Alkenes by Iodosylbenzene Catalyzed by Iron(III) Tetra(4-N-methylpyridyl)porphyrin in Methanoloxidation, dehydrogenation, ozonolysiscatalysis, phase-transfer catalysishydrocarbons (acyclic compounds)...
The reductive ozonolysis of an alkene gives a mixture of acetone and formaldehyde. What is the structural formula of the alkene? View Solution Doubtnut is No.1 Study App and Learning App with Instant Video Solutions for NCERT Class 6, Class 7, Class 8, Class 9, Class 10, Class 11 and ...
A) Draw the structure of the major organic product of the following reaction? B) is the product chiral or achiral? Draw the major organic product for the reaction shown below: Draw the alkene structure that produced the following compounds in a o...
The cleavage of alkenes to the corresponding carbonyl products is a widely employed method in organic synthesis, especially to introduce oxygen functionalities into molecules, remove protecting groups and tailor large molecules. Chemical methods available for alkene cleavage include, for instance, ozonolysis...
Mentel, T. F. et al. Formation of highly oxidized multifunctional compounds: autoxidation of peroxy radicals formed in the ozonolysis of alkenes – deduced from structure–product relationships.Atmos. Chem. Phys.15, 6745–6765 (2015). ArticleADSCASGoogle Scholar ...
We present such a difunctionalization of unactivated alkenes under simple conditions, through which olefins are converted into products in which functionalization has occurred with generality at positions 1 and 3 (Fig.1c). We achieved this by adapting electrophilic addition to alkenes as the basis for...
Semiempirical relations between structure and reactivity for the oxidation of alkenes by thallium(III) sulfate in aqueous mediumoxidation, dehydrogenation, ozonolysisNo abstract is available for this article.doi:10.1002/chin.197620129URBANEC, J.STRASAK, M....
oxidation, dehydrogenation, ozonolysisPorphyrin-catalysed epoxidation of alkenes with hydrogen peroxide has been shown to occur in the presence of non-oxidisable ligands and bases whereas previous work has suffered from destruction of base and ligand with concomitant excessive use of oxidant. The ...