Hydroxylamine hydrochloride Tert -Butyldimethylsilylchloride Dimethyformamide Triethylamine p- Toluenesulfonyl chloride O -TBS -N -tosylhydroxylamanie Phosphine, triphenyl 4-Benxyloxy-2-buten-1-ol DEAD Cesium fluoride Keywords: Oxime; Tosylhydroxylamine; Mechanism; Substrate scope; Precursors; Mitsunobu ...
oximetritiumHPLCMethods have been developed for the synthesis of (2 E )-1,1-dimethoxyalk-2-en-4-ols and (2 E )-4-hydroxyalk-2-enals by reaction of (2 E )-4,4-dimethoxybut-2-enals and Grignard compounds. Thermal isomerization of (2 E )-4-hydroxyalk-2-enals gave the corresponding...
photochemistry, radiation chemistry, chemoluminescencePhotolysis of the butenal oxime acetate (I) results in cyclization, forming the cyclopropanes (II) and (III).doi:10.1002/chin.198821162ARMESTO, D.HORSPOOL, W. M.LANGA, F.WILEY‐VCH Verlag GmbHChemInform...
ChemInform Abstract: The Aza‐di‐π‐methane Rearrangement of O‐Acetyl 2,2‐Dimethyl‐4,4‐diphenylbut‐3‐enal Oxime.doi:10.1002/chin.198821162cycloalkylphenyl derivativesring closure reactionsphotochemistry, radiation chemistry, chemoluminescenceD. ARMESTO...