Isobutene, cis- and trans-but-2-ene decrease the initial rate of ethanal pyrolysis. These inhibiting effects can be quantitatively interpreted by a kinetic scheme which appears as a new particular limiting case of a general inhibition or acceleration mechanism proposed and analyzed in 1966. The ...
Ethanal yields relative to alkene consumed were measured as 0.86±0.03, 0.85±0.07 and 0.66±0.02 for the reactions of ozone with Z-but-2-ene, E-but-2-ene and 2-methylbut-2-ene, respectively. For 2-methylbut-2-ene, the propanone yield was 0.35±0.03. Hydroxyl radical yields relative ...
Ethanal yields relative to alkene consumed were measured as 0.86±0.03, 0.85±0.07 and 0.66±0.02 for the reactions of ozone with Z-but-2-ene, E-but-2-ene and 2-methylbut-2-ene, respectively. For 2-methylbut-2-ene, the propanone yield was 0.35±0.03. Hydroxyl radical yields relative ...