Some fraction of diatom-produced HOBr and HOI may also form volatile Br2 and I2, which could transfer to the polar troposphere. The reaction of diatom-released reactive bromine and iodine with seawater DOM may represent the major mechanism in the formation of oceanic polybromo- and polyiodo-...
The kinetics of the reaction between p-methoxybenzeneboronic acid and iodine was studied in 5% aqueous MeOH at 25.1 deg. C. The results demonstrate that molecular iodine attacks a p-methoxybenzeneboronate anion in the rate determining step. Studies on the kinetics and mechanism of the reaction ...
A discussion is given on plausible mechanisms for the biosynthesis of representative organic bromine and organic iodine metabolites. Reaction pathways are illustrated throughout and comprehensive references are given.doi:10.1007/978-3-540-37055-0Alasdair H. Neilson...
A thermodynamic analysis of the suitability of alkaline-earth metals to the bromine and iodine cycles is presented. These cycles consist of: the redox reaction of bromine (iodine), thermal decomposition of bromate (iodate), hydrolysis of bromide (iodide) and the thermal dissociation of hydrogen ...
摘要: Reactions of LM(CO)3 complexes (M = Cr, Mo, W; L = 1,4,7-triazacyclononane) with bromine, iodine, and nitric acid. Syntheses of air-stable hydridocarbonyl and hydridonitrosyl complexes. Crystal structure of [LMo(CO)3Br](ClO4).H2O - ResearchGate...
Acids and esters are less easily brominated than aldehydes or ketones. Organometallic compounds can react with bromine to give bromides, but because organometallic compounds are frequently made from bromides the reaction with iodine to give iodides is of more synthetic significance. Bromine is widely ...
Decomposition is a serious competing reaction in adducts containing boron-bromine and especially boron-iodine bonds. Exchange reactions and trends in the n.m... CM Ironfield,MJ Barrington,R Kluger,... - 《Regional Anesthesia & Pain Medicine》 被引量: 36发表: 1972年 Spectroscopic and Quantum-Ch...
and aerosols in the troposphere and the stratosphere34. The model runs with the iodine and bromine chemistry schemes from previous studies36,41,42,43, including the photochemical breakdown of bromo- and iodo-carbons emitted from the oceans35and abiotic oceanic sources of HOI and I244. For this...
The program consists of six interrelated areas: (1) Reactions of iodine with alkenes and alkynes activated by radiative neutron capture and isomeric transi... EP Rack 被引量: 0发表: 1980年 Isotopic Effects of Br 80 and Br 82, as Formed by Radiative Capture; EFFET ISOTOPIQUE DANS LA CAPTUR...
443. The reaction of bromine trifluoride and iodine pentafluoride with carbon tetrachloride, tetrabromide, and tetraiodide and with tetraiodoethylene Banks A A,Emeleus H J,AszeldineR N,errigan V K.The reaction of bromine trifluoride and iodine pentafluoride with carbon tetrachloride, tetrabromide, ...