Bridge bonding in an electron deficient moleculeThe electronic distribution in the AlH 2 Al bridge of the dimethyl aluminium hybride dimer was computed through ab initio SCF calculation. Comparison with diborane shows an increased role of the ionic Al + H 2 2 Al + structures with respect to ...
Synthesis, Structure, Bonding, and Reactivity of Metal Complexes Comprising Diborane(4) and Diborene(2): [{Cp*Mo(CO)2}2{µ-η2:η2-B2H4}] and [{Cp*M(CO)2}2B2H2M(CO)4], M=Mo,W. Angew. Chem. Int. Ed. 2018, 57, 8079–8083. [CrossRef] 20. Krishnamoorthy, B.S.; Thakur...
Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame ComplexesboronbondingEDA-NOCVoxidative additionplatinumDiplatinum A‐frame complexes with a bridging (di)boron unit in the apex position were synthesized in a single step by the double oxidative addition of dihalo(di)borane ...
The structures of hydrogen-substituted diboron compounds, B_2H_6 (I), B_2H_4 (II), and B_2H_2 (III), have been continuously studied for the complete understanding of chemical bonding. Theoretical predictions of these compounds are summarized in Figure 1. Diborane(6) I, known as the ...
On the other hand, interaction of BH with HCN could be as H···H dihydrogen bond or H···N hydrogen bonding. Topological analyses of the electron density of optimized structures have been carried out using the atoms in molecules (AIMs) methodology. AIM calculations are indicating the HBD...
The chemical bonding in B 2 A 6 (A=H, BO, and BS) series is elucidated through the recently developed adaptive natural density partitioning (AdNDP). D 2h B 2 (BO) 6 and B 2 (BS) 6 were found to possess two bridging η 2 –BO or η 2 –BS groups, as well as four terminal ...
The electronic distribution in the AlH 2Al bridge of the dimethyl aluminium hydride dimer was computed through ab initio SCF calculation. Comparison with diborane shows an increased role of the ionic Al +H 22-Al + structures with respect to the usual covalent three-center bonds...