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What Is Psilocybin? Psilocybin (chemically known as 4-phosphoryloxy-N, N-dimethyltryptamine) and its active metabolite psilocin are the classic psychedelic compounds that belong to the group of hallucinogenic tryptamines. Psilocybin is in fungi as before Psilocybe, Conocybe, and Paneolus that are s...