BassanNilssonPetterssonL.ingentaconnectJournal of Molecular StructureM. Nyberg, A. Fohlisch, L. Triguero, A. Bassan, A. Nilsson, L.G.M. Pettersson, Bonding in metal-carbonyls: a comparison with experiment and calculations on adsorbed CO, J. Molec. Struct.-Theochem 762 (1-3) (2006) 123-...
The infrared spectrum of CF 3Mn(CO) 5 has been investigated in the gas phase. The C F stretching bands are found at 1045 and 1063 cm p−1 and the shapes of the band envelopes indicate that these are the frequencies of the e and a 1 modes, respectively. Using these and other data...
NATURE OF BONDING IN METAL CARBONYLS AS DETERMINED FROM THEIR VIBRATIONAL SPECTRA * The results of applying this treatment to the hexacarbonyls of chromium, molybdenum, and tungsten are presented and discussed. From the calculated values of the CO force constants it is evident that considerable 蟺-...
Infrared Studies of Group VIB metal Carbonyl Derivatives With three different proposals for the bonding in metal carbonyls, it was decided to look into the situation more thoroughly in order to see what other evi... RA Brown - 《Unt Theses & Dissertations》 被引量: 0发表: 1971年 The metal...
Previous ionization values for these molecules are compared with the new values, and the data are discussed in terms of simple molecular orbital schemes for the uppermost occupied orbitals. It is shown that the results may be interpreted in terms of strong π "back-donation" from metal to ...
Chemistry of the cyclopentadienylmetal Carbonyls V. (A) reactions of cyclopentadienylmolybdenum and-tungsten tricarbonyl halides with group va donor ligands : (B) cationic cyclopentadienylmolybdenum and -tungsten carbonyl derivatives wit... The reaction of C 5H 5Mo(CO) 3Cl and triphenylphosphine gives...
ChemInform Abstract: STRUCTURE AND BONDING IN TRANSITION-METAL CARBONYLS AND NITROSYLS. 2. GAS-PHASE ELECTRON DIFFRACTION REINVESTIGATION OF TRICARBONYLNIT... For decades, China has maintained State import monopoly in cultural products. The opaque State trading operations ensure a maximum level of flexibi...
a classification scheme and an approximate energy ordering which does not depend on any point-group symmetry that the cluster may have, and therefore provides a useful framework for discussion of the bonding in cluster compounds such as the boron hydrides and the transition metal cluster carbonyls....
Reactions of transition metal carbonyls with nucleophilic reagents: reactivity and bondingReactions of transition metal carbonyls with nucleophilic reagents: reactivity and bondingInitial investigations into the reactions of organomagnesium halide reagents with metal carbonyls indicate this reaction to be adaptable...
Values for the total metal-metal bond enthalpies, Sigma E(Re-Re), have been calculated for each cluster. Trends in Sigma E(Re-Re) are explored as a function of the cluster nuclearity, Jr, and the number of electrons donated by the ligands, Trends in CE(Re-Re) are also explored as ...