The off-symmetrical structure of the toluene···SbCl3 complex is a consequence of the off-centre location of σ-holes at the Sb atom. DFT-SAPT calculations have been used to determine the total interaction energies and their components. The characteristic features of the pnicogen bonding are ...
A right-angle cell was designed to produce ions in the vapour phase by means of a horizontal UV beam and tc transfer them in the liquid monomer using a vertical electric field, the negative electrode being immersed in the liquid.281 The mechanism probably involves the formation of a t-butyl...
G. P. Schiemenz·peri-Interactions in Naphthalenes, 14541Table 3. Selected salts R4X+Y−: Sums of the three largestand the three smallest angles C–X+–C (for comparison).EntryFormulaAngle∑(C–X+–C) [◦]Lit.largestsmallestangles106Me4N+HF2−C–N+–C328.8328.1[110]107Me4N+H2...