JACS: 可见/近红外响应的BODIPY形光笼分子 光笼分子(Photocage)也被称作“光可以去除的保护基团”,是一类含有光敏基团的分子,其可以在特定时间特定位置通过光刺激释放出特定的化合物,以实现特殊的功能。当光笼分子被修饰到底物上,底物的活性会被保护起来,因此在被激活前,底物不会与活性分子反应。而当光笼分子被激...
BODIPYPhotocageC=C bond cleavagevisible lightContrary to the cleavage of CX single bonds, the photoreaction of the C=C bonds of electron‐rich oxidative alkenes remains a challenge. This work presents a novel photoactivation of dialkenyl﹕ubstituted BODIPY photocages to release para﹉ydroxy ...
cage compoundschemical biologyphotolysissulfonamidesThe cover picture shows the photo-triggered un-"caging" of boron dipyrromethene (BODIPY)-based caged -aminobutyric acid (GABA). Investigation of the unexpected photo-instability of 2,6-sulfonamide-substituted derivatives of BODIPY fluorophore led to the ...
cage compoundschemical biologyphotolysissulfonamidesInvestigation of the unexpected photo-instability of 2,6-sulfonamide-substituted derivatives of the boron dipyrromethene (BODIPY) fluorophore led to the discovery of a photoreaction accompanied by multiple bond scissions. We characterized the photoproducts and...
In search of the perfect photocage: Structure–reactivity relationships in meso-Methyl BODIPY photoremovable protecting groups. J. Am. Chem. Soc. 2017, 139, 15168–15175. [Google Scholar] [CrossRef] [PubMed] Lachish, U.; Shafferman, A.; Stein, G. Intensity dependence in laser flash ...
Zhao, X.-L.; Ma, Y.-Z.; Wang, K.-Z. Synthesis, pH-induced “on–off–on” luminescence switching, and partially intercalative DNA-binding and DNA photocleavage properties of an β-d-allopyranoside-grafted ruthenium(II) complex.J. Inorg. Biochem.2012,113, 66–76. [Google Scholar] ...
JACS: 可见/近红外响应的BODIPY形光笼分子 CBG资讯公众号 2018-06-14 光笼分子(Photocage)也被称作“光可以去除的保护基团”,是一类含有光敏基团的分子,其可以在特定时间特定位置通过光刺激释放出特定的化合物,以实现特殊的功能。当光笼分子被修饰到底物上,底物的活性会被保护起来,因此在被激活前,底物不会与活性...