Binding energy shifts between atomic and solid phases for transition metals Cr, Mn, Fe, Co, and Ni have been obtained for 3p subshells from simultaneously recorded atomic vapor and solid state spectra. This experimental technique provides higher accuracy in comparison to separate measurements and ...
Total energies have been calculated and the importance of the Madelung energy has been demonstrated.doi:10.1016/0022-5088(87)90200-1Barbara SzpunarPaul StrangeW.E. WallaceElsevier B.V.Journal of the Less Common MetalsSzp:. B. Szpunar, P. Strange, and W.E. Wallace, Binding Energy and ...
Binding energy (BE) referencing is critical to the reliability of chemical analysis performed by X-ray photoelectron spectroscopy. Although the procedure is straightforward for metallic samples, no universal solution is available for insulators, wherein a build-up of positive charge during photoemission ...
On the basis of pseudopotential theory we obtain a simple expression for the interaction energy between ions in a metallic system replacing the ion form factor in the direct (Coulomb) interaction by the pseudo-ion form factor of the indirect (conduction mediated) interaction. This substitution can...
binding energy n.the energy required to separate particles from a molecule or atom or nucleus; equals the mass defect 同义词:separation energy 双语例句 The relations of the core binding energy of bonded atoms and their molecular enviroment are discussed.讨论了键合原子内壳层结合能和它的分子环境的...
Using constant-energy molecular-dynamics simulations, we have studied the binding energies and melting behavior of Ni, Pd, Au, and Agclusters (N=2-23) on the basis of the embedded-atom model and the second-moment approximation to the tight-binding method. The results show that the applicabili...
A systems approach to measuring the binding energy landscapes of transcription factors. Relative effect of extra-atomic relaxation on Auger and binding-energy shifts in transition metals and salts Core-level binding-energy shifts for the metallic elements ...
Binding energy (BE) referencing is critical to the reliability of chemical analysis performed by X-ray photoelectron spectroscopy. Although the procedure is straightforward for metallic samples, no universal solution is available for insulators, wherein
The σ-alkane complexes of transition metals, which contain an essentially intact alkane molecule weakly bound to the metal, have been well established as crucial intermediates in the activation of the strong C–H σ-bonds found in alkanes. Methane, the simplest alkane, binds even more weakly th...
Metals in biologyIsothermal titration calorimetryITCAllosteric coupling free energyIntracellular concentrations of transition metal ions are controlled at the transcriptional level by a panel of metalloregulatory proteins that collectively allow the cell to respond to changes in bioavailable metal concentration ...