S. Biphasic reaction system allows for conversion of hydrophobic substrates by amine dehydrogenases. ACS Catal. 4, 4021–4026 (2014). Article CAS Google Scholar Scalacci, N. et al. Unveiling the biocatalytic aromatizing activity of monoamine oxidases MAO-N and 6-HDNO: development of ...
Initially, the iron allyl complex II is forms from S-I by SN2 type displacement of the carbonate by Fe-complex. The stereochemistry of complex II is conserved through coordination to the CC double bond, thus preventing fast rotation around the CC single bond. Finally, attack of amin...
2-[3-(2-Fluorobenzyl)-1H-pyrazolo[4,3-b]pyridin-1-yl]-5-nitropyrimidine-4-amine795 mg (3.50 mmol) of the compound from Example 10A were initially charged in DMF (19 ml), 154 mg (3.85 mmol) of sodium hydride (60% in mineral oil) were then added and the mixture was stirred at ...
From our experience with primary amine-initiated polymerization of NCA,18- 20 this fact may be taken to imply that these polymer samples were relatively homogeneous with re- spect to molecular weight and composition. Bur21 has proposed a semi-empirical method for estimating the polydispersity index...
As the catalyst, secondary amine such as piperidine or pyrrolidine, or ammonium acetate can be used. The reaction can be performed at the reaction temperature of 0° C. to 150° C., preferably at refluxing temperature of the solvent. The fifteenth process can be performed by reducing in a...
cannot be increased in the potentiostatic electrolysis.The mechanism of the anode cyanation of N-benzylpiperidine was studied In methanol-water solution, anode cyanation of N-benzylpiperidine gives not only monocyanation product α-cyanoamine but also dicyanation product α, α-dicyanoamine and other...
cannot be increased in the potentiostatic electrolysis.The mechanism of the anode cyanation of N-benzylpiperidine was studied In methanol-water solution, anode cyanation of N-benzylpiperidine gives not only monocyanation product α-cyanoamine but also dicyanation product α, α-dicyanoamine and other...
Since PVP mainly interacts with the Bi3+ ions via its carbonyl or amine functional groups, it is reasonable to assume that PVP mainly influences the CB position of BiOBr-SMS while both BiOBr-MS and BiOBr-sMS have similar VB positions. As the band-gap energy of BiOBr-sMS is larger than ...
This one-pot process can be described in three distinct steps: (a) the dehydrogenation of the alcohol to the corresponding aldehyde; (b) the dehydrated condensation of the aldehyde with the primary amine to the imine through a hemiaminal intermediate; and finally (c) hydrogenation of the imine...
The excellent performance of the Pt/amine-functionalized MCFs is attributed to the formation of electron-deficient Pt species through strong interactions between the Pt nanoparticles and amine groups. Aerobic oxidation of benzyl alcohol: Influence from catalysts basicity, acidity, and preparation methods ...