Detailed reaction mechanisms are proposed based on evidence from tandem mass spectrometry experiments and bimolecular gas‐ phase reactions, supported by extensive quantum chemical calculations. Formation of intermediate Grignard compounds by decarboxylation is seen to be the rate‐ determining step of the ...
Reactions of azathiabenzene anion with electrophiles. Formation and x-ray analysis of novel heterocyclic compounds from the reaction with carboxylic ester The anion (2) generated from 9-methyl-10-aza-9-thiaphenanthrene (1) reacted with carboxylic ester to give the spiro compounds (9a), (9b)...
organic catalysis , pharmaceutical chemistry , photochemistry , proteins , quantum chemistry , radical reactions , self assembly , sensors , spectroscopy , natural products , synthesis , crystal structures , reaction mechanisms , peptide , combinatorial , carbohydrate, CSIRO , csiro publishing , publicati...
This catalytic system could be extended to the coupling reactions between various substituted benzenes and alkenes through the direct aromatic C−H bond activation. In the reaction of benzene with ethyl acrylate under O2 (1 atm), the best turn-over number (TON) of Pd(OAc)2 reached was 121...
- 《Organic & Biomolecular Chemistry》 被引量: 0发表: 2016年 Reactions of arenediazonium o-benzenedisulfonimides with aliphatic triorganoindium compounds European journal of organic chemistryBarbero, M.; Cadamuro, S.; Dughera, S.; Ghigo, G. Reactions of arenediazonium o- benzenedisulfonimides...
The Effect of Structure upon the Reactions of Organic Compounds. Benzene Derivatives Publication » The Effect of Structure upon the Reactions of Organic Compounds. Benzene Derivatives. LP Hammett - 《J.am.chem.soc》 被引量: 1476发表: 1937年 Relative Rates of the Aluminum Chloride-catalyzed Benz...
Organic Synthesis: (Diacetoxyiodo)benzene is commonly used in organic synthesis reactions. Its purpose in this field involves its ability to act as an oxidizing agent, facilitating various chemical transformations. The mechanism of action in organic synthesis involves the transfer of oxygen atoms from ...
Electron-transfer chain reactions leading to regioselective alkylations of benzenes bearing electron-withdrawing substituents can be observed with alkyl ha... C Wang,GA Russell,WS Trahanovsky - 《Journal of Organic Chemistry》 被引量: 49发表: 1998年 An Efficient Synthesis of Brominated C-Aryl Glyc...
关键词: organic chemistry, review reactions of organo‐metal compounds DOI: 10.1002/chin.200043273 被引量: 2021 年份: 2000 收藏 引用 批量引用 报错 分享 全部来源 免费下载 求助全文 国家科技图书文献中心 (权威机构) Wiley ACS dx.doi.org NCBI 查看更多 相似文献 参考文献 引证文献...
I. Cox.Synthesis and reactions of cyanovinyl-substituted benzenediazonium salts for nonlinear optical.Journal of Organic Chemistry. 1988Schilling M L , Katz H E ,Cox D I. Synt hesis and reactions of cyanovinyl - substit uted benzenediazonium salt s for nonlinear optics[J ] . J . Org. ...