Two new one-dimensional (1D) Zinc Metal organic frame works, [Zn (BDC) (DMF) RT] (or Zn-MOF-1) and [Zn (BDC) (DMF) MW] (or Zn-MOF-2), where H2BDC = Benzene 1, 4 di-carboxylic acid, DMF = N, N-dimethylformamide, RT= Room temperature, MW= Microwave, have been synthesized...
Benzene-1, 4-dicarboxylic acidMicrowave, Photo-luminescenceCrystallographic studiesTwo new one-dimensional (1D) Zinc Metal organic frame works, [Zn (BDC) (DMF) RT] (or Zn-MOF-1) and [Zn (BDC) (DMF) MW] (or Zn-MOF-2), where H2 BDC = Benzene 1, 4 di-carboxylic acid, DMF = N,...
A new coordination polymer, [Pb2(C8H4O4)2(C5H9NO)2]n, has been prepared by the reaction of Pb(NO3)2 with benzene-1,4-dicarboxylic acid (H2bdc) in 1-methylpyrrolidin-2-one (nmp). There are two types of Pb ions in the crystal structure, one coordinated by five O atoms and the...
A new coordination polymer, [Pb2(C8H4O4)2(C5H9NO)2]n, has been prepared by the reaction of Pb(NO3)2 with benzene-1,4-dicarboxylic acid (H2bdc) in 1-methylpyrrolidin-2-one (nmp). There are two types of Pb ions in the crystal structure, one coordinated by five O atoms and the...
A new coordination polymer {[Cd(C_(21)H_(14)N_6)(C_8H_4O_4)]·H_2O}_n(1) was synthesized by an elaborate design via the reaction of 3-(2,6-di(pyrazin-2-yl)pyridin-4-yl)-1H-indole(bppi),1,4-benzene-dicarboxylic acid(H2bdc) and cadmium(Ⅱ) nitrate in CH_3OH/H_2O...
4'-Bis(benzoimidazol-1 -yl)bibenzeneSolvothermal reactions of CdCl_2-2.5H_2O with 4,4'-bis(benzoimidazol-l-yl)bibenzene (bimbb) and 1,4-benzenedicarboxylic acid (1,4-H2bdc), 4,4'-biphenyldicarboxylic acid (4,4'-H_2bpdb), 5-methyl-1,3-benzenedicarboxylic acid (5-Me-l,3-H2bdc...
of an anionic carboxyl ligand and a neutral N-donor ligand (BIX=1,4-bis((1H-imidazol-1-yl)methyl)-benzene; H3BTC=1,2,3-benzene-tricarboxylic acid; H2BDC=1,3-benzene-dicarboxylic acid (isophthalic acid); H2PDC=3,4-pyridine-dicarboxylic acid; H3IDC=4,5-imidazole-dicarboxylic acid). Com...
(2,2′:6′,2″‐terpyridin‐4′‐yl)benzenesulfonate, H2glu = glutaric acid, H2(1,3‐bdc) = benzene‐1,3‐dicarboxylic acid, H2(1,2‐bdc) = benzene‐1,2‐dicarboxylic acid], have been prepared under hydrothermal conditions and characterized by elemental analysis, IR and single‐crystal...
The title compound, {[Zn4(C8H4O4)3(OH)2(C12H6N2O2)2]·2H2O}n, has been prepared hydrothermally by the reaction of Zn(NO3)2·6H2O with benzene-1,4-dicarboxylic acid (H2bdc) and 1,10-phenanthroline-5,6-dione (pdon) in H2O. In the crystal structure, a tetra...