The invention provides extended bisphosphonate-based metal complexes using benzene1,4-bis(bisphosphonic acid) (BBPA), an analog of benzene 1,4-dicarboxylic acid (BDC). Hydrothermal synthesis of BBPA with the bioactive metals Ca, Zn, and Mgleads to four crystals phases, namely, BBPA-Ca forms ...
Two new Zn (II) bdc Metal-Organic Frameworks based on benzene 1, 4-dicarboxylic acid: Synthesis, Crystal structures, Luminescent properties and Electrochemical studiesTwo new one-dimensional (1D) Zinc Metal organic frame works, [Zn (BDC) (DMF) RT] (or Zn-MOF-1) and [Zn (BDC) (DMF) ...
bdc)(dabco)] (Hbdc = benzene-1,4-dicarboxylic acid, dabco = diazabicyclo[2.2.2]octane) is reported. The [Zn(bdc)(dabco)] polymer has a high CH sorption capacity of up to 3.8 mol of benzene per formula unit. The heat of sorption has been determined, and its dependence on the ...
The invention provides extended bisphosphonate-based metal complexes using benzene1,4-bis(bisphosphonic acid) (BBPA), an analog of benzene 1,4-dicarboxylic acid (BDC). Hydrothermal synthesis of BBPA with the bioactive metals Ca2+, Zn2+, and Mg2+ leads to four crystals phases, namely, BBPA-...
The invention provides extended bisphosphonate-based metal complexes using benzene1,4-bis(bisphosphonic acid) (BBPA), an analog of benzene 1,4-dicarboxylic acid (BDC). Hydrothermal synthesis of BBPA with the bioactive metals Ca2+, Zn2+, and Mg2+ leads to four crystals phases, namely, BBPA-...
Two new Zn (II) bdc Metal-Organic Frameworks based on benzene 1, 4-dicarboxylic acid: Synthesis, Crystal structures, Luminescent properties and Electrochemical studiesdoi:10.1016/j.matpr.2020.03.298B M OmkaramurthyG KrishnamurthyNL Prasad
Reactions of benzene‐1,4‐dicarboxylic acid (H 2 BDC) and pyridine (py) with Zn II or Co II yielded two new coordination polymers, namely, poly[(μ 4 ‐benzene‐1,4‐dicarboxylato‐κ 4 O : O ′: O ′′: O ′′′)(pyridine‐κ N )zinc(II)], [Zn(C 8 H 4 O 2 )(C ...
Ultrafiltration-level polyacrylonitrile (PAN) flat sheet membranes were chemically modified through cross-linking and hydrolysis to provide a suitable surface for the growth of a selective layer composed of a Zn benzene-1,4-dicarboxylic acid (Zn(BDC)) metal-organic framework (MOF). Unlike typical ...
Reactions of benzene-1,4-dicarboxylic acid (H2BDC) and pyridine (py) with ZnII or CoII yielded two new coordination polymers, namely, poly[(μ4-benzene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′)(pyridine-κN)zinc(II)], [Zn(C8H4O2)(C5H5N)]n, (I), and catena-poly[aqua(μ3...
and Ho ( 5 ); L=BDC 2 or BDC 2 /NO 2 -BDC 2- ) and [Tm(NO 2 -BDC) 1.5 (H 2 O)]·H 2 O ( 6 ), have been synthesized using mixed ligands of benzene-1,4-dicarboxylic acid (H 2 BDC) and the in situ generated 2-nitro-benzene-1,4-dicarboxylic acid (NO 2 -BDC 2-...