Boron-11 quadrupole coupling parameters of (CH3)4NB3H8 and KB3H8 at 298 K are, respectively: νQ = 58 kHz, η = 0; νQ = 0.48 MHz, η = 0.76; where νQ = e2qzzQ/2h. The B3H8 anions undergo motions such that all
Ammonium Octahydrotriborate (NH4B3H8): New Synthesis, Structure, and Hydrolytic Hydrogen Release. Zhenguo Huang,Xuenian Chen,Teshome Yisgedu,Edward A. Meyers,Sheldon G. Shore,Ji-Cheng Zhao. Inorganic Chemistry . 2011Huang, Z.; Chen, X; Yisgedu, T; Meyers, E.A.; Shore, S.G.; Zhao, ...
Ammonium Octahydrotriborate (NH4B3H8): New Synthesis, Structure, and Hydrolytic Hydrogen Release A metathesis reaction between unsolvated NaB3H8 and NH4Cl provides a simple and high-yield synthesis of NH4B3H8. Structure determination through X-ray sing... Zhenguo,Huang,Xuenian,... - 《Inorganic...
The crystal structure was determined for the compound with R = H. The latter reacts with N-halogeno succinimides to give the halogeno derivatives [RuR(B3H8)(CO)(PPh3)2] (R = Cl, Br, I) and with tBuNC in dichloromethane to give [RuClH(CNtBu)2(PPh3)2]. Sodium dialkyldithio...
structure (solids and liquidsChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.doi:10.1002/chin.200725023...
Extended strong dihydrogen bonds were observed in pure [(NH3)2BH2]B3H8 through crystal structure solution based upon powder X-ray analysis. Pyrolysis of [(NH3)2BH2]B3H8 leads to the formation of hydrogen gas together with appreciable amounts of volatile boranes below 160 °C....
The chemistry of the octahydrotriborate anion [B3H8]The review integrates data on the structure, methods of synthesis, reactivity, and coordination properties of the octahydrotriborate anion.doi:10.1134/S0036023614130026Bykov, A. Yu.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy...
Synthesis, structure and chemistry of low-boron containing molybdaborane: Arachno-[Cp*Mo(CO)(2)B3H8]Low-boronMolybdenumButterflyMetallaboraneCluster compoundsRoom temperature photolysis of [Cp*Mo(CO)(3)Mel, 1 with excess of [BH3.THF] led to the isolation of hydrogen-rich arachno-[Cp*Mo(...
MOLECULAR-STRUCTURELOW-TEMPERATUREDIFFUSION BARRIERSolvate-free sodium octahydrotriborate, NaB3H8, is prepared on a 20 gram scale from sodium amalgam and diborane in diethyl ether. This substance, which is chemically related to borohydride-based compounds being investigated as hydrogen storage materials,...
This represents a controlled transition metal mediated synthesis of a higher borane moiety from a mononuclear precursor. The crystal structure of [WH 3(Pme 3) 3B 3H 8] has been determined.doi:10.1016/0022-328X(88)80106-2Peter D. GrebenikJohn B. LeachMalcolm L.H. GreenNeil M. Walker...