导读: 近日,厦门大学的徐海超课题组在Angew. Chem. Int. Ed.中发表论文,报道一种全新的烷基或芳基烯烃参与的电化学azidocyanation反应方法学,进而成功完成一系列具有氰基与叠氮基取代烷烃分子的构建。 Electrochemical Azidocyanation of Alkenes Y. Zheng, H. Xu,Angew
We report herein an unprecedented electrochemical strategy for alkene azidocyanation that is compatible with both alkyl and aryl alkenes. This is achieved by harnessing the finely‐tuned anodic electron transfer and the strategic selection of copper/ligand complexes. The reactions of aryl alkenes were ...
导读: 近日,厦门大学的徐海超课题组在Angew. Chem. Int. Ed.中发表论文,报道一种全新的烷基或芳基烯烃参与的电化学azidocyanation反应方法学,进而成功完成一系列具有氰基与叠氮基取代烷烃分子的构建。 Electrochemical Azidocyanation of Alkenes Y. Zheng, H. Xu,Angew. Chem. Int. Ed.2023, ...
A conceptually new, efficient, and metal-free approach for the challenging azidocyanation of unactivated alkenes is presented. The strategy of intramolecular distal cyano migration is combined with alkene difunctionalization for the first time. A variety of useful azido-substituted alkyl nitriles are ...
ChemInform Abstract: Copper‐Catalyzed Intermolecular Azidocyanation of Aryl Alkenes.nitriles (benzene compounds)azides (benzene compounds)catalysis, phase‐transfer catalysisNo abstract is available for this article.doi:10.1002/chin.201506088Xu, Li
Copper-catalyzed intermolecular azidocyanation of aryl alkenesXu, L.Mou, X. Q.Chen, Z. M.Wang, S. H.CHEMICAL COMMUNICATIONS- ROYAL SOCIETY OF CHEMISTRYX. Li, X. Mou, C. Zhimin and W. Shaohua, Copper-catalyzed intermolecular azidocyanation of aryl alkenes, Chem. Commun., 2014, 50, ...
doi:10.1002/chin.201506088LiSch.XuSch.Xue-QingSch.MouSch.Zhi-MinSch.ChenSch.Shao-HuaSch.WangSch.WileyChemInformX. Li, X. Mou, C. Zhimin and W. Shaohua, Copper-catalyzed intermolecular azidocyanation of aryl alkenes, Chem. Commun., 2014, 50, 10676....