The rate constant for the reaction H+H2O2→OH+H2O was newly determined to be 3.5×107 dm3 mol−1 s−1 by observing the Cl2− absorbance in pulse radiolysis experiments involving very pure acidic aqueous solutions of chloride ions and hydrogen peroxide. A reaction mecha...
Equations are derived for the accumulation and dark-decay kinetics. These are in agreement with experimental data obtained for H-atom abstraction reactions by CH 3 radicals in methanol glass at 77 K.doi:10.1016/0009-2614(79)87288-7Elsevier B.V.Chemical Physics Letters...