turn, recent first-passage approaches have been used to account for the finite backward rate constant of binding for multiple particles17,19, but do not consider competing binding partners for diffusants, which is necessary for biological realism and is the advantage of LBA. Finally, as all cell...
Volume term of work of critical nucleus formation in terms of chemical potential difference relative to equilibrium one The work of formation of a critical nucleus is sometimes written as W=n{\\Delta}{\\mu}+{\\gamma}A. The first term W_{vol}=n{\\Delta}{\\mu} is called the vo......
As the hcp iron has lower free energy than the bcc iron51, the bcc structure would finally transform to hcp if time is long enough to reach equilibrium. This two-step nucleation scenario for inner core formation suggests that there may be a metastable phase transition from bcc to hcp iron ...
Equilibrium ConstantThe equilibrium constant of a certain reaction is based on the free energy change which is signified by the symbol {eq}\Delta G {/eq}. At the state of equilibrium, the value of {eq}\Delta G {/eq} is equal to zero....
In the high energy domain, one of the long standing problems is finding clear experimental signals of gluon saturation, which is a signature of quasi equilibrium between gluon splitting and gluon fusion in dense nuclear systems. Gluon saturation has been predicted from QCD long time ago [1, 2]...
1a). The silica activity for Qz-saturated aqueous fluid is always higher than the silica activity at Tlc–Srp equilibrium (Fig. 1a); this Si activity gradient is a typical driving force for the Si-metasomatism of mantle rocks at the crust–mantle interface (Frost and Beard 2007; Manning ...
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The initial conditions are in equilibrium \(X_{i} = F,i \ne j~\forall i\) with only a single variable which is slightly perturbed \(X_{j} = F + 0.005 + 0.01\varepsilon\) with \(\varepsilon \sim U(0,1)\), drawn from a random uniform distribution in \(\left[ {0,1} \ri...
Here \(\Delta {G}_{{\rm{alloy}}}^{\mathrm{B}}\) is the excess grand potential of the two bulk phases in equilibrium. The Gibbs free energy and chemical potentials required to calculate \(\Delta {G}_{{\rm{alloy}}}^{\mathrm{B}}\) are obtained from ThermoCalc thermodynamic databas...
W. Phase equilibrium modelling of the amphibolite to granulite facies transition in metabasic rocks (Ivrea Zone, NW Italy). J. Metamorph. Geol. 37, 935–950 (2019). Article CAS Google Scholar Ciazela, J. et al. Thin crust and exposed mantle control sulfide differentiation in slow-...