doi:10.1002/chin.198339303organo‐nickel compoundsThe unstable species Ni(CO)//3 N//2 is generated in solution by UV photolysis of Ni(CO)//4 in N//2 -doped liquid Kr in a specially designed high-pressure cell. The reaction rate has been monitored over the temperature range 112-127 K....
If the pressure ratio r = 0, then the SF exceeds the value of ideal selectivity 𝛼12 (=15 in this example). At non-zero permeate pressure, the SF also grows monotonically with increasing the Peclét number. In this case, two intervals can be distinguished: at small Peclét numbers (B...