This dissertation focuses on the development of environmentally benign coatings involving the application of the Michael addition reaction and its adducts in the composition of polymeric resin binders. The Michael addition of primary amines to 伪,尾-unsaturated esters was briefly investigated to synthesize...
Application of a transition-metal-mediated stereospecific Michael reaction equivalent to the synthesis of alloyohimbonealkaloidsNo abstract is available for this article.doi:10.1021/jo00354a015StephenA.GodleskiEdwinB.VillhauerWILEY‐VCH Verlag GmbH
Michael adducts were formed with good to excellent enantioselectivities, so the addition of diethyl acetamidomalonate to β-nitrostyrene took place with up to 92% ee, while the reaction of diethyl acetoxymalonate with chalcones proceeded with up to 99% ee. Using diethyl bromomalonate as the ...
PS-b-PAEFc films were applied as electrochemically-responsive heterogeneous catalysts based on the ferrocenium moieties for Michael addition reaction between methyl vinyl ketone and ethyl 2-oxocyclopentanecarboxylate (E2OC) in 0.1 M NaPF6/EtOH. The catalytic activities of thin films were similar ...
ChemInform Abstract: APPLICATION OF REACTION FIELD THEORY TO THE CALCULATION OF SOLVENT EFFECTS ON THE T‐BUTYL CHLORIDE SOLVOLYSIS, AND ON THE ME4N(+)CL(‐) ION PAIRsolvolysis, hydrolysishalogen compounds (acyclic compoundsquaternary ammonium compounds (acyclic compounds...
Applying cold discharge plasma can potentially alter plants' germination characteristics by triggering their physiological activities. As a main crop in many countries, soybean was examined in the present study using cultivars such as Arian, Katoul, Saba
Cu(I)-Catalyzed Tandem Benzyldiazoester Coupling with Terminal Alkyne—Allene Formation—Michael Reaction: Application to the Syntheses of Oxa and Azacycles. ChemInform Abstract: Cu(I)-Catalyzed Tandem Benzyldiazoester Coupling with Terminal Alkyne—Allene Formation—Michael Reaction: Application to the ...
The bicyclic guanidine can catalyze the transesterification reaction, Michael addition, Henry reaction and the ring-opening polymerization reaction, wherein the bicyclic guanidine catalyzed surface modification of cellulose comprising the steps of: a cellulose is dissolved in water, made of a thin film,...
ChemInform Abstract: APPLICATION OF REACTION FIELD THEORY TO THE CALCULATION OF SOLVENT EFFECTS ON THE MENSCHUTKIN REACTION OF TRIPROPYLAMINE WITH METHYL IODIDEdoi:10.1002/chin.197610122MICHAELH.ABRAHAMRAYMONDJ.ABRAHAMWileyChemischer Informationsdienst
of α, β-unsaturated ketone. Cys can destroy the space effect by Michael addition reaction, which makes the fluorescence intensity changes. Furthermore, the probe featured excellent selectivity and high sensitivity (the detection limit was 0.52 μM) by addition of Cys. Moreover, this probe ...