internal rotationrotational spectroscopyThe microwave spectrum of o-methyl anisole (2-methoxytoluene), CH3OC6H4CH3, has been measured using a pulsed molecular jet Fourier transform microwave spectrometer operating in the frequency range 2 - 26.5 GHz. Conformational analysis using quantum chemical ...
Product Name: 2,3,4,5,6-PENTAFLUOROANISOLE Synonyms: 1,2,3,4,5-Pentafluoro-6-methoxybenzene;1,2,3,4,5-Pentafluoro-6-methoxy-benzene;2,3,4,5,6-Pentafluoranisol;Anisole, 2,3,4,5,6-pentafluoro-;Benzene,pentafluoromethoxy-;Methyl pentafluorophenyl ether;pentafluoromethoxy-benzen;Pentafluor...
The organic phase was separated and washed with water (5 × 11) to remove t-BuOH and ammonia, followed by drying over anhyd. K2CO3. Evaporation of solvent, followed by distillation gave 1-methoxy-1,4-cyclohexadiene (176 g, 80%) b.p. 50°/35 mm (lit.59 40°/20 mm). Similarly ...
Friedel-Crafts acylation catalyzed by zeolite Hβ to synthesize 4-methoxybenzophenone A three-dimensional large pore zeolite Hβ is used in the benzoylation of anisole instead of the classical Lewis acid catalysts to synthesize the important... B Yuan,WH Qiao,J Yan,... - 《Journal of Dalian...
COMPOSITION CONTAINING SYN-2-(2-AMMOIUMTHIAZOLE-4-YL)-2-METHOXY-IMINOACETIC CHLORIDE AND PROCESS FOR PREPARATION THEREOF PURPOSE: To provide stable compositions containing the above mentioned compounds useful as important intermediates for preparing antibiotics by coupling wi... HL Albregt,JHMH Kooistra...
PhOMe has a functional methoxy group (-OCH3) on the benzene ring, has an aromatic odor, and is commonly used as a chemical solvent and an intermediate product in organic synthesis. Uses Hydrogenation reaction of anisole Anisole can be efficiently converted to cyclohexane over Ni/Al2O3 ...
methylbenzene; 2-CHLORO-6-METHOXYTOLUENE; 2-Chloro-6-methoxytoluene~2-Methoxy-6-chlorotoluene; 2-Methoxy-6-chlorotoluene; 2-METHYL-3-CHLOROANISOLE; 3-chloro-2-methoxyanisole; 3-CHLORO-2-METHYLANISOLE; 6-Chloro-2-methoxytoluene; Anisole, 3-chloro-2-methyl-; Benzene, 1-chloro-3-methoxy-2-...
The complex is significantly more electron-rich than the complexes of toluene and xylene and therefore undergoes addition reactions with a much broader range of electrophiles. Likewise, the anisolium complex that is formed following electrophilic addition is significantly more amenable to nucleophilic ...
The effect of alkali metal ions (Li+, Na+, K+, Cs+) on the reactivity of toluenethiolate anion in the demethylation of 2-methoxy-1,3-xylyl-18-crown-5, 2-methoxy-1,3-xylyl-24-crown-7 and the model compounds anisole and 2,6-dimethylanisole was investigated in dimethylformamide (+3.3...
For all catalysts, the deoxygenated product selectivity, i.e., towards benzene and toluene, exhibited a decreasing trend with TOS, similar to that observed for the anisole conversion (see Fig. 4), in contrast to the phenolic product selectivity, i.e., phenol, cresol and dimethyl phenol, ...