Diazonium salt ionic liquid [aniline LiNf2 HCl anilinium triflate solvent free aq NaNO2 diazotization]Dai, S
The in situ produced HNO2 from an excess of NaNO2/HCl was trapped by alkyl aryl radical to form oximes in the E configuration form. The presence of tin/tin chloride mixture in the reaction of the aryl diazonium salts with methyl vinyl ketone produced Michael products along with β-aryl ...
The reactivity of the aryldiazoniumacetates was evaluated by addition of KI (Sandemeyer reaction) or furan (Gomberg-Bachmann reaction).Results: Using 1 equivalent of KI and 1.2 equivalents of NaNO2, substituted iodoarenes were obtained with poor to good yields. We observed in this two-step ...
The in situ produced HNO2 from an excess of NaNO2/HCl was trapped by alkyl aryl radical to form oximes in the E configuration form. The presence of tin/tin chloride mixture in the reaction of the aryl diazonium salts with methyl vinyl ketone produced Michael products along with β-aryl ...