By definition, disproportionation is an oxidation–reduction reaction in which the same compound acts as both the oxidizing and reducing agent (Atkins et al., 2010). Compounds susceptible to disproportionation will be inherently unstable, even in the absence of other redox-active compounds. Hydroxylami...
The oxygen reduction reaction (ORR) involves the electrochemical reduction of molecular oxygen into water. From:Coordination Chemistry Reviews,2022 Add to Mendeley Also in subject areas: Engineering Physics and Astronomy Discover other topics Chapters and Articles ...
Unlike the isomerase reaction, the oxidoreductive reaction consists of two steps (an oxidation and a reduction) and requires cofactors. Though seemingly redundant, this mechanism prevents the undesired reverse reaction through thermodynamic coupling to cofactor equilibria. Therefore, we used the oxidoreduct...
A method of performing an oxidation reaction in which an alkali hypohalite is used as an oxidizing agent which comprises: carrying out the oxidation reaction in an aqueous medium with concurrently distilling off a solvent used in the reaction as the reaction proceeds under a reduced pressure.The ...
BGZ has definite pharmacological effects, such as anti-tumor, anti-oxidation, antibacterial, anti-inflammatory, anti-depression, estrogen level regulation, bone growth promotion, nerve protection, and influence on the liver [19]. Its active ingredients, psoralen, and 5-methoxypsoralen, have become ...
Organic Reaction Mechanisms · 2002: An annual survey covering the literature dated January to December 2002 This volume is the 38 th in this classical series. In every volume the content is divided in the different classes of organic reaction mechanisms:An exper... AC Knipe - Organic Reaction...
Overall, the highly selective redox sensor has a distinct response to DO concentration and offers a novel and cost-effective approach for monitoring or predicting DO in eutrophic waters. Keywords: oxidation–reduction potential; electrochemical sensor; coastal hypoxia; input variable; LSTM network; ...
In this work, the application of advanced oxidation processes (AOPs) for the removal of antibiotics from water has been reviewed. The present concern about water has been exposed, and the main problems derived from the presence of emerging pollutants hav
The mechanism involved is well known, wherein, the substrate initially undergoes an one-electron oxidation in the presence of a redox mediator and transforms into a radical cation followed by abstraction of a H-atom from the substrate by the mediator and converting it into a radical, which can...
Thermodynamic equilibrium where concentrations of substrates and products do not change with time is a fundamental limitation of enzymatic reactions catalyzed by isomerases1. Biotransformations involving an isomerization reaction are therefore constrained by the underlying thermodynamic equilibrium, which often le...