We identify a new motif for BsubPc crystals that occurs when the intermolecular interactions between the axial phenoxy segment and the BsubPc ligand are increased. We present two methods for achieving this new motif, one is through addition of a pi-Br interaction and the other is through ...
However, strategies for tailoring the molecular interactions of aptamers rely largely on combinatorial selection techniques Gold et al 1995, Osborne and Ellington 1997 rather than rational design. While the study of distinct intermolecular interactions can reveal general tactics for the organization of ...
09 December 2015 SMARCAL1 Negatively Regulates C-Myc Transcription By Altering The Conformation Of The Promoter Region Tapan Sharma, Ritu Bansal, Dominic Thangminlen Haokip, Isha Goel & Rohini Muthuswami SMARCAL1, a member of the SWI2/SNF2 protein family, stabilizes replication forks ...
This powerful effect originates in its structural peculiarity: even though L-proline possesses both hydrophobic and hydrophilic moieties, the intermolecular hydrophobic stacking of its pyrrolidine rings greatly enhances its hydrophilicity29. This ring structure also significantly reduces the loss of internal...
Oxidation and formation of the A8-A9 disulfide cross link enhanced calprotectin's susceptibility to proteolysis by neutrophil proteases. We propose that reversible disulfide cross-linking of calprotectin occurs during inflammation and affects its structure and function. Its increased susceptibility to ...
intermolecular interactionThe mechanically compliant single crystals have attracted massive attention. However, the related reports on the single crystals composed of metal-organic complexes remain scarce. In this study, we synthesized a series of isostructural single crystals of Zn II complexes that ...
We experimentally and theoretically demonstrated that, governed by the competition between GO-solvent intermolecular interaction and GO intramolecular interaction, GO nanosheets displayed deverse disperse properties in different organic solvents, thereby determining their distinct assembly behaviors. Moreover, the...
Analysis of frontier molecular orbitals reveals that intramolecular charge transfer (ICT) occurs in the first excited state both for C343 monomer and complex. The results of optimized geometric structures indicate that the intramolecular hydrogen bonding interaction is strengthened while the intermolecular ...