metallaboranerheniumThe photolysis of [M2(CO)10] (M=Re or Mn) with BH3thf at room temperature yields arachno-1 and 2, [(CO)8M2B2H6] (1: M=Re, 2: M=Mn). Both the compounds show a butterfly structure with seven skeletal electron pairs and 42 valence electrons. This result ...
1) BH3, THF2) H2O2, NaOHanti-mark alkene double OH added OsO4, H2O2syn addition oxymercuration 1) Hg(OAc)2, H2O2) NaBH4 form cyclo ZnCu, CH2I2 alcohol oxidationalcohol->cabocylic acid H2CrO4, H2SO4 alcohol to ketone H2CrO4, H2SO4 alcohol->aldehyde(no further) CH2Cl2, ClCrO3-,...