Starting from aliphatic alcohols or phenols the title reaction has been elaborated providing challenging alkylaryl ethers which are difficult to access by conventional Mitsunobu conditions.doi:10.1002/chin.201538085Shen, XiaoNeumann, Constanze N.Kleinlein, Claudia...
在文献中看到增效测定中，用N,N-二甲基甲酰胺和alkylarylpolyglycolether（3：1）溶解增效剂（PBO,DEF,...
99 Heterocyclic triflates are also reactive, but the yield may be strongly dependent upon the structure of the reagent.107 Lower-order Gilman reagents, although effective in coupling reactions with vinyl triflates, cause only SO bond cleavage in reactions with aryl triflates. The majority of ...
Alkyl Ether Bond, Formula & Molecular Structure Browse by Lessons Esters: Formation & Uses Reflex Reaction | Overview, Purpose & Apparatus Ester Bond | Definition & Chemical Formula Alkoxy Group | Overview, Examples & List What is an Aliphatic Ester? - Definition, Synthesis & Solvent ...
An alkyl and/or aryl silyl ether capped polyether surfactant useful in cleaning compositions. The polyether is described in conjunction with automatic dishwashing detergent composition having improved chlorine bleach stability comprising:(a) an active chlorine containing compound selected from the group consi...
PURPOSE:To advantageously obtain an aralkyl aryl ether by reacting an alkoxyphenol with an aralkyl halide in a polar solvent. CONSTITUTION:An alkoxyphenol is reacted with an aralkyl halide using, preferably a basic compound or a phase-transfer catalyst, especially a phase-transfer catalyst such ...
Synthesis and Structure-activity Relationships of Varied Ether Linker Analogues of the Anti-tubercular Drug (6S)-2-Nitro-6-{[4-(trifluoromethoxy)benzyl]oxy... Novel extended side chain nitroimidazooxazine analogues featuring diverse linker groups between two aryl rings were studied as a potential st...
Gelation properties of poly(aryl ether)dendrons bearing long alkyl chainsDendronLow-molecular-weight gelator3,4,5-Trihydroxybenzoic acidVan der Waals forceHansen solubility parameterPoly(aryl ether) dendrons ( 2 ) bearing long alkyl chains can undergo physical gelation in various organic solvents, ...
(5–17, 67–93%) in excellent yields. However, aryl alkenes were not well adapted to this reaction, only styrenes containing electron-rich substituents can give the corresponding products in lower yields (18–20). Other activated olefins, bearing ether, ester, amide, and amine groups could ...
The recently determined crystal structure of benzylsuccinate synthase from T. aromatica T1 revealed that the smaller subunits participate in conformational dynamics of the large subunit controlling generation and utilization of the glycyl radical, which is assumed to pass the radical on to a neighbouring...