Baldovino Pantaleón O,Hernández-Ortega S,et al.Alkyl-and arylthiolation of aryl halides catalyzed by fluorinatedbis-imino-nickel NNN pincer complexes[NiCl2{C5H3N-2,6- (CHNArf)2}].Advanced Synthesis and Catalysis. 2006Baldovino-Pantaleon, O.,Hernandez-Ortega, S.,Morales-Morales, D.Alkyl-and...
Known reactions are optimized for specific electrophiles and are not amenable to interchangeably varying electrophilic substrates that are sourced from common alkyl building blocks, such as amines, carboxylic acids and halides3,4,5. These limitations restrict the types of alkyl substrate that can be ...
Next, we evaluated the scope of the two kinds of alkyl halides, which revealed a range of radical precursors could be employed. Firstly, we test the scope of radical precursors by using 2-(but-3-en-1-yl)naphthalene as the alkene component and EtBr as the alkyl bromide component. As show...
Pd–PEPPSI–IPent has proven to be an excellent catalyst for the Negishi cross-coupling reaction of secondary alkylzinc reagents with a wide variety of aryl/heteroaryl halides. Importantly, β-hydride elimination/migratory insertion of the organometallic leading to the production of isomeric coupling pr...
6.8Alkyl halides Analkyl halideis another name for a halogen-substituted alkane. The carbon atom, which is bonded to the halogen atom, has sp3hybridized bonding orbitals and exhibits atetrahedral shape. Due toelectronegativitydifferences between the carbon and halogen atoms, the σcovalent bondbetween...
N , N , N ′, N ′-Tetramethylethylenediamine-Copper Salt-catalysed Coupling of Aryl Grignard Reagents with Alkyl and Aralkyl Halides N,N,N′,N′-Tetramethylethylenediamine-Copper Salt-catalysedCoupling of Aryl Grignard Reagents with Alkyl and Aralkyl Halides. Onuma K,Hashimoto H. ... K ...
It would appear that such (aryloxy)alkylamines may represent a novel class of 5-HT1D receptor agonists.doi:10.1021/jm970507tDukat, Malgorzata... Dukat, Malgorzata,Law, Ho,Kamboj, Rajender,... - 《Journal of Medicinal Chemistry》 被引量: 80发表: 1997年 1-Naphthyl and 4-indolyl arylalky...
The surface active and aggregation behavior of ionic liquids of type [C n mim][X] (1-alkyl-3-methylimidazolium (mim) halides), where n = 4... Nilesh,M.,Vaghela,... - 《Colloid & Polymer Science》 被引量: 38发表: 2011年 Formation of Thermotropic and Lyotropic Liquid Crystals of...
ChemInform Abstract: CARBONYLATION OF ARYLLITHIUM REAGENTS IN THE PRESENCE OF ALKYL HALIDES: ONE-POT SYNTHESIS OF DIARYLALKYL CARBINOLS AND DERIVATIVEScarbonylation, decarbonylation, C‐formylationDie Carbonyliertlng von Phenyllithium (I) in Gegenwart von Bromiden (II) liefert die Alkohole (III) und ...
Although iron-catalyzed cross-coupling reactions of arylmagnesium halides with alkyl halides are well established and proceed effectively under a variety o... CL Sun,H Krause,A Fürstner - 《Advanced Synthesis & Catalysis》 被引量: 29发表: 2015年 Expedient Synthesis of Chiral α‐Amino Acids thr...