Efficient Acylation of Benzimidazoles with Esters and Identification of a Tetrahedral Hemiacetal Alkoxide IntermediateKenneth J. Fitch
This mechanism involves an ortho addition on the Grignard reagent, leading to a trienic magnesium alkoxide intermediate (4), which decomposes by a ... Claude,Bernardon,Alain,... - 《Journal of the Chemical Society》 被引量: 3发表: 1980年 Stereoselective Cross-Coupling of Grignard Reagents and...
The structure of the leaving terpene influences the orientation of consecutive decompositions during collisionally activated decomposition (CAD) of [M–H]− ions which pass through a glucose alkoxide intermediate ion. This apparent „memory effect” can be rationalized by considering the production ...
Alkoxide is also employed as an intermediate chemical in the manufacture of adhesives that are widely used in electronic & electrical, building & construction, and personal care sectors. Thus, rise in demand for adhesives is likely to propel the demand for alkoxide in Asia Pacific in the near ...
Define Alkoxide ion. Alkoxide ion synonyms, Alkoxide ion pronunciation, Alkoxide ion translation, English dictionary definition of Alkoxide ion. n. An organic compound in which the hydrogen of the hydroxyl group of an alcohol has been replaced by a metal
G.Aksnes,Fayez Y.Khalil,Piotr J.Majewski.Kinetic Study of Alkoxide Promoted Decomposition of Organic Phosphonium Compounds Evidence for Hexacovalent Intermediate[J].Phosphorus,Sulfur,and Silicon and the Related Elements,1977,3(2):157-161.G.Aksnes,,Fayez Y.Khalil,,Piotr J.Majewski.Kinetic Study ...
JanataThe structure of intermediate I in Reaction IVcorresponds to a dimeric form of this aggregate which is closer to the structure it occurs in nature. In the above study, complete transmetalation (Reaction V) was found to be favorable only for M = Na; however, some effects, such as a...
A number of processes for the formation of insoluble metal alkoxides are disclosed. In one embodiment, there is disclosed a two step process wherein a halide of an at least divalent metal is reacted with an appropriate alcohol in the first step. In the second step, the intermediate compound...
A number of processes for the formation of insoluble metal alkoxides are disclosed. In one embodiment, there is disclosed a two step process wherein a halide of an at least divalent metal is reacted with an appropriate alcohol in the first step. In the second step, the intermediate compound...
Chloroketones and chlorohydrins are versatile intermediate products in synthesis of bioactive compounds [1]. Hydroxyketones are used for the synthesis of p... O. M. Lezina,S. A. Rubtsova,AV Kuchin - 《Russian Journal of Organic Chemistry》 被引量: 0发表: 2011年 Mass spectrometry of inorgan...