OXIDATION OF ALKANE TO ALKENEProvided is a process for converting an alkane to an alkene. The process comprises (a) contacting the alkane and either (i) an oxidizing electrophile comprising a main group element in oxidized form, or (ii) an oxidant and a reduced form of the oxidizing ...
The selective oxidation of hydrocarbons is a challenging reaction for synthetic chemists, but common in nature. Iron oxygenases activate the O–O bond of dioxygen to perform oxidation of alkane and alkenes moieties with outstanding levels of regio-, chemo- and stereoselectivity. Along a bioinspired ...
Using butene as an example, there are four isomers for the alkene (1-butene, cis-2-butene, trans-2-butene, and isobutene), whereas there are only two for the corresponding alkane (n-butane and isobutane). Alkenes are defined by the carbon-to-carbon double bond, and it is this bond ...
A study of active sites for alkene and alkane oxidation over Mo and V mixed oxide catalysts using 18O tracer and Raman ... OH Numata - 《Topics in Catalysis》 被引量: 0发表: 2001年 ChemInform Abstract: A Study of Active Sites for Alkene and Alkane Oxidation over Mo and V Mixed Oxide...
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Neumarm R ,Abu~Gnim C.A ruthenium heteropolyanion as catalyst for alkane and alkene oxidation d Chem Sac Chem Comraun,1989:1324～ 1325R. Neumann, C. Abu-Gnim, A ruthenium heteropolyanion as catalyst for alkane and alkene oxidation, J. Chem. Soc., Chem. Commun. 18 (1989) 1324....
Utilizing a procedure developed by Rutherford and Knochel <91TL441>, Michael-type addition of organometallics to the nitroalkene (246) afforded, after acidic work-up, the nitroalkene (247) in 75–95% yield. The purified nitroalkane was treated withn-butyllithium and the resulting lithium nitro...
src="/content/R087346538702213/xxlarge945.gif" alt="agr" align="BASELINE" border="0">-Bi2Mo3O12were exchanged with 18O via a reduction–oxidation method and the catalytic oxidation of alkene or alkane using 18O2. The Raman bands of the catalysts shifted to lower frequencies by the exchan...
Alcohols react with hydrogen halides to form haloalkanes. Can alcohol be synthesized? Alcohols can be prepared by the hydration of alkenes or by the reduction of aldehydes, ketones, acids, and esters. Does alcohol give baeyer's test? Ethanol and secondary alcohols which contain CH3—CH(OH)R ...
United States Patent US10501390 Note: If you have problems viewing the PDF, please make sure you have the latest version ofAdobe Acrobat. Back to full text