Imamoto T. Reduction of saturated alkyl halides to alkanes[M ] / / Flem ing I. Reduction. Oxford: Pergamon Press, 1991: 7932809.Imamoto T. Reduction of saturated alkyl halides to alkanes[ M ]//Fleming I. Reduction. Oxford:Pergamon Press, 1991:793-809....
A couple of examples of alkyl halides How do you name cycloalkanes? Cycloalkanes are just alkanes in a ring. It is as simple as that. They are named according to how many carbon atoms they have in their ring. For example, cyclopropane is made up of three carbon atoms. The prefix cyclo-...
In order to understand the reactions of the halogenoalkanes we need to be able to classify them. There are four different types. 1. Methyl halides. The halide is attached only to the methyl group. 2. Primary halides. The carbon where the halogen is bonded is only attached to one other ...
Each carbon atom forms 4 bonds (either with other carbon atoms or with hydrogen or halogen atoms). Each hydrogen and halogen atom is connected to a single carbon atom. Haloalkanesare also known ashalogenalkanesand (less commonly) asalkyl halides. ...
Part XXIX. Halogen atom abstraction from alkyl halides by trimethyltin radicals in the gas phase Mixtures of trimethyltin hydride and halogenoalkanes have been irradiated in the gas phase by a medium pressure mercury lamp. A very rapid reaction ensues in which a halogen atom in the original ...
Subsequently, a series of alkyl halides, such as iodomethane (E3), bromoacetonitrile (E4), allyl bromide (E5), and benzylic halide (E6) were used, the corresponding products (K36–K39) were generated in moderate to good yields. When 4-methoxybenzoyl chloride (E7) was used, the desired ...
9 RegisterLog in Sign up with one click: Facebook Twitter Google Share on Facebook alkane (redirected fromAlkanes) Thesaurus Medical Encyclopedia Related to Alkanes:Hydrocarbons al·kane (ăl′kān′) n. Any member of the alkane series. ...
Application to the homogeneous and heterogeneous reduction of alkyl halides. J. Am. Chem. Soc. 109, 6788–6795 (1987). Article CAS Google Scholar Saveant, J. M. Electron transfer, bond breaking, and bond formation. Acc. Chem. Res. 26, 455–461 (1993). Article CAS Google Scholar ...
(B) This work: ligand-enabled silver-catalyzed site-selective C–H benzylation of alkanes with N-triftosylhydrazones as the donor carbene precursor, leading to alkyl aromatics. EWG, electron-withdrawing group; EDG, electron-donating group; r.r., regioisomeric ratio of 3°, 2° and 1° C–...
Using DMF, acetonitrile and alcohols as cosolvents, both polyfluoroalkyl iodides, such as Cl(CF2)nI (n=4, 6, 8; 1a-c) and F(CF2)nI (n=6, 8; 1d, e), and polyfluoroalkyl bromides, such as Cl(CF2)6Br (3b) and F(CF2)8Br (3e), react with sodi... FH Wu,BN Huang -...