Current Progress in the Asymmetric Aldol Addition Reaction. Chem. Soc. Rev. 2004, 33 (2), 65–75. A Stereochemical Model for Merged 1,2- and 1,3-Asymmetric Induction in Diastereoselective Muraiyama Aldol Addition Reactions and Related Processes. J. Am. Chem. Soc. 1996,118 (18), 4322–...
This reaction has come to be known as the Aldol reaction, or “aldol addition reaction” to distinguish them from cases where water is lost to give a new C-C double bond (that’s the aldol condensation, see part 3) This type of reaction can also work for ketones (see below) and othe...
In a process for preparing an optically active 尾-hydroxyester derivative by enantioselective aldol addition reaction between an aldehyde and a ketene silylacetal, the enantioselective aldol addition reaction is performed in the presence of an organic base and a platinum-containing catalyst composed of ...
Mukaiyama羟醛反应(Mukaiyama Aldol Addition) 反应机理下载链接:http://chem.kingdraw.cn/Shortlink?id=20200902143852 Mukaiyama羟醛反应,又称向山羟醛反应,是指在四氯化钛等路易斯酸介导下,羰基化合物形成的烯醇硅醚与醛、酮的羟醛反应,产物为β-羟基醛、酮。此处烯醇硅醚为烯醇负离子的等效体,但其亲核性不够强...
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IntroductionDiastereoselective Aldol Addition ReactionsEnantioselective CatalysisConclusiondoi:10.1002/9783527613267.ch08Erick M. CarreiraWiley‐VCH Verlag GmbHE. M. Carreira, “Aldol Reaction: Methodology and Stereochemistry,” in Modern Carbonyl Chemistry , Ed.: J. Otera, Wiley-VCH, Weinheim, 2000 , ...
(1996), ChemInform Abstract: Reagent Control in the Aldol Addition Reaction of Chiral Boron Enolates with Chiral α-Amino Aldehydes. Total Synthesis of (3S, 4S)-Statine (VIII). ChemInform, 27: no. doi: 10.1002/chin.199609041 Author Information Dip. Chim. Org. Ind., Univ. Milano, I-...
2 – The Aldol Addition Reaction2 – The Aldol Addition ReactionClayton H. HeathcockDepartment of Chemistry, University of California, Berkeley, CaliforniaAsymmetric SynthesisC. H. Heathcock, "The aldol addition reaction," Asymmetric Synthesis, vol. 3, p. 111, 1984.Heathcock...
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The addition of an enolate to an aldehyde molecule is called the "aldol addition reaction." A subsequent step of heating the aldol in the presence of a base compound produces the "aldol condensation product."What is an Aldol? An aldol is a class of organic compounds containing a 3-hydroxy...