The alcohol has a floral, herbaceous odor, reminiscent of lilac, and is prepared by a Grignard reaction of benzylmagnesium chloride and acetone. It is used in perfumery for various flower notes.. Suppliers(129) Properties MSDS NMR Spectrum Phenethyl acetate CAS:103-45-7 MF:C10H12O2 Liquid...
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Aromatic•inaromaticalcohols(orphenols)theOHisattacheddirectlytothering•anOHonasidechainofaringbehavesasatypicalaliphaticalcohol Thefirsttwocompoundsareclassifiedasaromaticalcohols(phenols)becausetheOHgroupisattacheddirectlytothering.CLASSIFICATIONOFALCOHOLS Aliphatic•generalformulaCnH2n+1OH-providedtherearenorings...
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One-pot reactions that combine non-enzymatic and biocatalytic transformations represent an emerging strategy in chemical synthesis. Some of the most powerful chemoenzymatic methodologies, although uncommon, are those that form a carbon–carbon (C–C) bond and a stereocenter at one of the reacting car...
and FM via a general linkage (amide formation, Fig.1d). More importantly, with the unique mechanistic pathway40(Fig.2a), the light-induced PANAC conjugation presents excellent selectivity to primary amines groups, while being orthogonal to other common functional groups, including alcohols, phenols,...
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Oligosaccharides, one of the most abundant biopolymers, are involved in numerous biological processes. Although many efforts have been put in preparative carbohydrate chemistry, achieving optimal anomeric and regioselectivities remains challenging. Herei
Reaction conditions: a mixture of 1a (0.10 mmol), 2 (0.15 mmol), K2CO3 (0.12 mmol), and DQ (0.12 mmol) in CH2Cl2 (1.0 mL) was stirred at room temperature under N2 for 12–24 h Full size image Fig. 3 Scope of biaryl biphenols. Reaction conditions: a mixture...
Sulphated zirconia catalyzed acylation of phenols, alcohols and amines under solvent free conditions. J. Mol. Catal. A: Chem. 2007, 276, 230-234. 4. Wang, S.; Matsumura, S.; Toshima, K. Sulfated zirconia (SO4/ZrO2) as a reusable solid acid catalyst for the Mannich-type reaction ...