27Al NMR spectra of aluminum-tri-sec-butoxide (Al(O-sec-Bu)3) dissolved in several molar ratios of diacetone alcohol were measured. The spectrum of Al(O-sec-Bu)3 dissolved in diacetone alcohol showed the formation of five-coordinated structural units from original four-coordinated ones. This...
Synthesis of Alumnia Particles from Combustion of Al-Tri-Sec-Butoxide in Diffusion FlamesJ.T. JohannessenS.E. PratsinisHans Livbjerg
This MOCVD process is based on the thermal decomposition of aluminium-tri-sec-butoxide (ATSB). The effect of the deposition temperature (within the range 290–420 °C), the precursor vapour pressure (5.33×10-32.67×10-2 kPa), and the gas flow (6.512.5 1 min-1) of the MOCVD process...
The precursor structures of aluminum-tri-sec-butoxide (Al(O-sec-Bu) 3 ) chemically modified with alkanolamines, such as mono-, di-, and tri-ethanolamines, were investigated using 27 Al NMR. Those spectra revealed that the addition of these alkanolamines led to the structural change around Al...