OxidationAlcoholGold nano-particles confined in the walls of mesoporous silica (GMS) catalysts were successfully prepared by a novel and simple technique utilizing thioether functional groups in the walls of mesoporous silica to anchor HAuCl 4. Calcination of the materials removed organic moieties and ...
Highly Selective Aerobic Oxidation of Alcohol Catalyzed by a Gold (Ⅰ) Complex with an Anionic Ligand. Guan Bing-Tao,Xing Dong,Cai Gui-Xing, et al. Journal of American Culture . 2005Guan Bingtao,Xing Dong,Cai Guixing,Wan Xiaobin,Yu Nan,Fang Zhao,Yang Liping,Shi Zhangjie.Highly selective...
The adsorption method results in high dispersion of palladium probably as mononuclear or oligonuclear species on alumina surface. These palladium species are transformed to small Pd nanoparticles (ca. 5â nm), which are probably the true active species, during the course of alcohol oxidation...
A sugar-discriminating dinuclear copper(II) complex was investigated for its ability to promote aerobic oxidation of primary benzylic alcohols in the presence of TEMPO and base. The transformation of benzyl alcohol to benzaldehyde was chosen as exploratory model reaction. The constitution of the ...
Aerobic oxidation of benzyl alcohol to benzaldehyde catalyzed by carbon nanotubes without any promoterLuo, J.Yu, H.Wang, H.Wang, H.Peng, F.CHEMICAL ENGINEERING JOURNAL -LAUSANNE-Aerobic oxidation of benzyl alcohol to benzaldehyde catalyzed by carbon nanotubes without any promoter[J] . Jin Luo,...
Highly selective and stable polybenzoxazine-based carbon nanosheet supported Pd catalyst for aerobic benzyl alcohol oxidation Yan Hao Da-jie Zhao Qing-hu Tang Chemical Papers(2023) Solvent-free catalytic oxidation of toluene over heterogeneous CeMnOx composite oxides ...
Efficient NO Equivalent for Activation of Molecular Oxygen and Its Applications in Transition-Metal-Free Catalytic Aerobic Alcohol Oxidation tert-Butyl nitrite (TBN) was identified as an efficient NO equivalent for the activation of molecular oxygen. The unique property of TBN enabled TEMPO-cata... ...
Model system used for reaction optimization. Conditions used for optimization of the catalyst can be found in Table1 Full size image Table 1 Oxidation of 1-phenylethane-1,2-diol promoted by different catalysts Full size table Stability study of catalyst ...
Ilyas, M.,Sadiq, M.Liquid-Phase Aerobic Oxidation of Benzyl Alcohol Catalyzed by Pt/ZrO2. Chemical Engineering . 2007M. Ilyas, M. Sadiq, Liquid-phase aerobic oxidation of benzyl alcohol catalyzed by Pt/ZrO2, Chem. Eng. Technol. 30 (2007) 1391-1397....
Under optimized reaction conditions, the MnO2 catalyst showed a superior catalytic performance in the highly selective oxidation of benzyl alcohol as compared to other manganese oxide materials such as MnO, Mn2O3 and Mn3O4. Moreover, a very stable catalytic activity as a function of cycling test...