ChemInform Abstract: Formation of Adamantylideneadamantane‐1,2‐dioxetane via Photoinitiated Electron Transfer Under the Participation of Tetracyanoethylene.heterocyclic 4‐membered ringsIrradiation of adamantylideneadamantane (I) in the presence of oxygen and tetracyanoethylene gives the oxetane (II) and ...
Adamantylideneadamantane (I) is converted to the dioxetane (II) by photosensitized oxygenation, using uranyl nitrate as sensitizer.doi:10.1002/chin.198827076VOLOSHIN, A. I.SHARIPOV, G. L.KAZAKOV, V. P.TOLSTIKOV, G. A.WILEY‐VCH Verlag GmbHChemInform...
In the CL imaging techniques, adamantylideneadamantane 1,2-dioxetane (Adox) has been adopted as a stable core structure of chemiluminophores. That is, Adox is an essential seed compound to design a chemiluminophore with a desired molecular function. To support developments of real-time CL ...
Institute of Chemistry, Academy of Sciences of the USSRA. I. VoloshinInstitute of Chemistry, Academy of Sciences of the USSRV. S. GumerovaInstitute of Chemistry, Academy of Sciences of the USSRB. M. LermanInstitute of Chemistry, Academy of Sciences of the USSR...
Functionalized adamantylideneadamantane 1,2dioxetanes: investigation on stable and inherently chemiluminescent compounds as a tool for clinical analysis - Hummelen, Luider, et al. - 1987Hummelen JC, Luider TM, Wynberg H (1987) Functional adamantylidene adamantane 1,2-dioxetane: Investigations of ...
Adamantylideneadamantane peroxide. A stable 1,2-dioxetaneFirst page of articledoi:10.1107/S0567740877011352J. HessA. VosJohn Wiley & Sons, Ltd.Acta Crystallographica
A new chemiluminescent reaction has been observed, appearing in solution in the reaction of a damantylideneadamantane-1,2-dioxetane with trialkylalanes and dialkylaluminum hydrides.doi:10.1007/BF00954071G. A. TolstikovAcademy of Sciences of the USSR...
The corresponding dioxetanes which, instead of being substituted at the 5' or 7', or at the 5' and 7' positions, instead contain a 4' methylene group, are also disclosed, as are intermediates for all these 3-substituted adamant-2'-ylidenedioxetanes, and their use as reporter molecules ...
represent an organic substituent that does not interfere with the production of light when the dioxetane compound is enzymatically cleaved and that satisfies the valence of the dioxetane compound's 4-carbon atom, with the provisos that if R1 and R2 represent individual substituents the R2 substitue...
Complexation of the chelate both with dioxetane and with adamantanone (2), the product of decomposition of dioxetane, have an important effect on chemiluminescence (CL) in thermal decomposition of adamantylideneadamantane-1,2-dioxetane (1) in the presence of Eu(fod)3 chelate. The stability ...