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famille-rose dish (lot 564) decorated with flying bats and shou medallions is a typical example incorporating textual and pictorial motifs to maximize the auspiciousness: the pronunciation of bat in Chinese, fu, is the same as the character for good fortune. The second group of Cixi...
One of the molecules we modeled was F2(di-fluorine gas), which has an electron pair that holds the two F atoms together. The molecule showed a strange behavior: in the eyes of every chemist, F2was by definition a covalent bond since the two bonded atoms are identical to each other. How...
2. Thr118, Tyr147, and Lys151 form the characteristic signature of a typical SDR catalytic center. Ser119, Glu120, and Arg277 are distinct features of the UXS group of enzymes (Fig. 1B, supplemental Fig. S1). We analyzed binding of the substrate by carrying out an energy-minimized ...
Moreover, distinct from the typical C–C bond-forming condensation catalyzed by KS domains, how a KS releases a polyketide chain through aminoacylation has never been structurally characterized before. In this work, we determined the structures of CalA3 using cryo-electron microscopy. CalA3 is a...
In a previous work by some authors of the present paper26, it is shown that a quantum simulation of a typical, industrially relevant organometallic compound would require over 2000 qubits. Selecting the appropriate PD technique could result in the reduction of qubit requirements significantly. A ...
The nuclear displacements along specific vibrational modes are of the order of 15% of a typical chemical bond between carbon, oxygen, and nitrogen atoms and about 30% for bonds involving hydrogen atoms. The time required for the hole transfer corresponds to less than half a vibrational period ...
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