2D MOF precursorsActivated porous carbonNanosheetsElectrochemical double layer capacitorsSymmetric supercapacitor cellsIn this work, a novel Cu-MOF of translational 2D (4,4) layers has been designed and afforded as hierarchically stacking lamellae with interspace. Cu-MOF is initially employed as precursors...
Unlike the 2D Ni H-MOF, the XRD pattern of the bulk Ni H-MOF contains additional peaks at 18.3, 27.7, 35.3, and 36.9 ⁰ compared to the simulated XRD pattern. These are assigned to the crystallographic planes that are parallel to the stacking direction of layers, resulting in a bulky ...
2D MOF nanosheets have several advantages, such as high purity, ultrathin layer thickness, well refined surface area, abundant exposed unsaturated metal sites, and adjustable chemical composition compared with their 3D counterpart [97]. The drug-loading capacity of 2D MOF nanosheets make them benefici...
However, the ordered stacking of MOF nanosheets showed partially or blocked micropores, therefore hot drop coating method was preferred to efficiently fabricate class 2 membranes for these materials. Their membranes showed impressive selectivity for the H2/CO2 pair (~ 260) at 120 °C with line...
Due to the strong intermolecular interaction between MXene films, the over-stacking of nanosheets may occur while constructing the protective layer. The introduction of spacers is a simple and easy solution. This method can also be used to introduce other functional materials into the protective lay...
However, the ordered stacking of MOF nanosheets showed partially or blocked micropores, therefore hot drop coating method was preferred to efficiently fabricate class 2 membranes for these materials. Their membranes showed impressive selectivity for the H2/CO2 pair (~ 260) at 120 °C with ...
we demonstrate with DFT how we can exploit this knowledge for tunable external control over the magnetism in a substrate-supported 2D MOF. First, the mean-field Hubbard model showed that decreasing molecule-molecule hoppingtincreases the local magnetic moments. Hopping is proportional to orbital overl...
x additive was vacuum filtered on a polycarbonate substrate forming a horizontal stacking of laminated MXene sheets (Fig. 6C). The prepared membranes were then soaked in chlorine chloride-ethylene glycol (ChCl-EG) and then spin-coated to remove the excess of ChCl-EG, forming Ti3...
43 formed a 2D–3D nanocomposite through the growth of Ni-MOF-74 (NiDOBDC) nanocrystals with a uniform particle size on GO sheets. The latter facilitated the growth of NiDOBDC nanocrystals, leading to the creation of 3D nanoarchitectures that retained the porous nature of NiDOBDC. As shown ...
Firstly, the intrinsic pore of MOF allows facile diffusion of Zn2+, while their insulating nature ensures the deposition of Zn under the MOF-protective layers. Secondly, the surface structure of MOF can be judiciously tuned to regulate the interaction between the Zn surface and electrolytes. ...