2-methoxyethlacrylateBlood compatibilityHydrophilic material 2-methoxyethylacrylate (MEA) was grafted onto polysulfone (PSF) membrane via Michael addition reaction. The 1H nuclear magnetic resonance (1H NMR), Attenuated total reflectance Fourier transform infrared spectroscope (ATR-FTIR) and X-ray ...
Javakhishvili, I.; Tanaka, M.; Ogura, K.; Jankova, K.; Hvilsted, S. Synthesis of Graft Copolymers Based on Poly ( 2- Methoxyethyl Acrylate ) and Investigation of the Associated Water Structure. Macromol. Rapid Commun. 2012, 319-325....
Irrespective of the degree of polymerization, the molecular mobilities of the 2-hydroxyethyl methacrylate (HEMA) moieties are smaller than those of the 2-methoxyethyl acrylate (MEA) moieties. Preventing the polar functional groups of the foulants and materials from forming a hydrogen-bonding network ...
EXPERIMENTAL Materials Acrylonitrile (AN) (CDH, 99%) and 2-methoxy- ethyl acrylate (MEA) (Aldrich, 98%) were passed through alumina column to remove inhibitor, vacuum distilled and kept below 5 C prior to use. 2-Bromo- propionitrile (BPN) (Aldrich, 97%), CuCl (Aldrich, 97%) was ...
Subsequently, well-defined triblock copolymers of HEA and 2-methoxyethyl acrylate (MEA) with the general microstructure P(HEA)-block-P(MEA)-block-P(HEM and P (HEA)-block-P (HEA-grad-MEA)-block-P(HEA) are synthesized via RAFT, using previously prepared HEA-based homopolymers with degrees ...
The nitroxide mediated copolymerization of 2-hydroxyethyl acrylate (HEA) and 2-methoxyethyl acrylate (MEA) is reported. The copolymerization kinetics followed the persistent radical model and revealed the formation of well-defined ideal random copolymers (rHEA= 0.93 ± 0.09;rMEA= 0.95 ± 0.09). SEC...
The influence of alcohol and alcohol/water solutions on the radical copolymerization kinetics of 2‐hydroxyethyl methacrylate (HEMA) with 2‐methoxyethyl acrylate (MEA) is studied using pulsed‐laser‐polymerization coupled with size exclusion chromatography. It is found that MEA incorporation into the ...
Poly颅(2-methoxyethylacrylate) (PMEA) shows excellent blood compatibilitybecause of the existence of intermediate water. Various modificationsof PMEA by changing its main or side chain's chemical structureallowed tuning of the water content and the blood compatibility ofnumerous novel polymers. Here, ...
17.97MPa. The CO 2 +2-MEA system exhibited type-I phase behavior and was modeled using the Peng-Robinson equation of state. The phase behavior data were reported for poly(2- methoxyethyl acrylate) [P(2-MEA)] in supercritical CO 2 and dimethyl ether (DME), as well as for the P(2-...
Poly(ethylene oxide)-poly(2-methoxyethyl acrylate) diblock copolymers (PEO-b-PMEA) are synthesized by RAFT aqueous dispersion polymerization of MEA using poly(ethylene oxide) macromolecular chain transfer agent as a reactive steric stabilizer. Both segments are well-known to be bio- and blood-...