Effective synthesis of 2,5-dicyanofuran and 2,5-bis(aminomethyl)furan from DFF was obtained by Xu's group [66,67]. The oximation of DFF produced 2,5-diformylfuran dioxime as an intermediate, which could be further converted into 2,5-dicyanofuran and 2,5-bis(aminomethyl)furan by dehydrati...
The reaction order with respect to DFF and intermediate product 2,5-diformylfuran dioxime(DFFD) was 1.06 and 0.16,and the reaction activation energy was 64.07 k J·mol~(-1)and 59.37 k J·mol~(-1)respectively. After the reaction,the ionic liquid was easy to separate, recover and recycle....