Mo2Ni2Cp2(CO)2 is the only compound so far reported to have the cubane-type Mo-Ni-S core.5TakashiDepartmentShibaharaDepartment&DepartmentHisaoDepartmentKuroyaDepartmentInformaworldJournal of Coordination Chemistry
Compound 1 is one-dimensional consisting of [V4O12]4− rings connected through [Cu(phen)(H2O)]2+ subunits. The structure of 2 is two-dimensional, with a network constructed from one-dimensional chains of corner-sharing [VO4]3− tetrahedra, which are linked through [Co(phen)(H2O)]2+...
The [C6H2(COO)4]4– anion adopts a μ10 coordination mode. Compound 1 reveals short Ba–Ba contacts of 426.46(2) pm, whereas the Pb–Pb distance of 411.01(6) pm in 2 is larger than twice the van der Waals radius.RobertoInstituteKöferstein...