1,3,5-苯三甲酸 CAS号: 554-95-0 英文名: Trimesic acid 英文别名: H3BTC;1,3,5-BENZENETRICARBOXYLIC ACID;BENZENE-1,3,5-TRICARBOXYLIC ACID;benzene-1,3,5-tricarboxylate;1,3,5-Tricarboxybenzene;1,3,5-Trimesic Acid;Benzotrienes;rimesic acid;JACS-554-95-0;TRIMESIC ACID 中文名: 1,3,...
K ey w ords 1,3,52Benzenetricarboxylate ,Metal 2organic com plex ,Framew ork 图式1 BTC 的结构图Scheme 1 The structure of BTC 在配位化学领域中,金属簇无机2有机杂化配位聚合物因其在催化、磁性、光 学、主客体交换和分子导体等方面所具有的潜在应用性,成为近年来的一个研究 热点[1,2]。金属2...
特别是刚性的多羧基苯配体1,3,52均苯三羧 酸 图式1BTC的 结构图 Scheme1The structure ofBTC 根(BTC,benzenetricarboxylate),由于其能够与金属离子构筑出多种形式不同、刚性和热稳定性良好的配 位聚合骨架而得到了广泛的研究 8 ,已有许多具有光、电、磁学性质的化合物被合成出来。本文将分别 就BTC配位的方式和...
BenzenetricarboxylateX-ray structural analysesThe product from the reaction between Cd(NO3)2·4H2O and 1,3,5-benzenetricarboxylic acid (H3btc) in DMF at 95°C depends on the reaction time, with [Cd(Hbtc)(H2O)2] 1 and [Cd(Hbtc)(DMF)2] 2 isolated after heating for 10min, the latter...
特别是刚性的多羧基苯配体 1,3,5-均苯三羧酸根 BTC benzenetricarboxylate 其结构见图式 1 所示。由于其能够与金属离子构筑出多种形式不同、刚性和热稳定性良好的配位聚合骨架而得到了广泛的研究[8] 已有许多具有光、电、磁学性质的化合物被合成出来。本文将分别就 BTC 配位的方式和特点、BTC 配合物的合成、...
The reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with NiCO3 under hydrothermal conditions afforded a new 2D complex Ni3(BTC)2(-H2O)2·6H2O, which possesses an infinite double-layered structure. The layer is comprised of syn-syn carboxylate- and aqua oxygen-bridged Ni3 units that...
A new metal-organic framework (MOF), {[Zn3(btc)2(bimb)2(H2O)2](H2O)3} n ( 1 ), where H3btc =1,3,5-benzenetricarboxylate and bimb = 4,4′-bis(1-imidazolyl)biphenyl, has been synthesized and characterized using single-crystal X-ray diffraction, IR spectroscopy, elemental, ...
Coordination polymers of macrocyclic oxamide with 1,3,5-benzenetricarboxylate: syntheses, crystal structures and magnetic propertiesElectronic supplementary information (ESI) available. CCDC reference numbers 800812–800817. For ESI and...Solvothermal reactions of mixed ligands H3BTC and macrocyclic oxamide...
Iron 1,3,5-benzenetricarboxylate Synonyms Fe-BTC; Copper Benzene-1, 3, 5-tricarboxylate; iron(3+) ion benzene-1, 3, 5-tricarboxylate, Basolite F300 Chemical Identifiers Linear FormulaC9H3FeO6 MDL NumberMFCD11656051 EC No.N/A Beilstein/Reaxys No.N/A ...
1,3,5-benzenetricarboxylatewhite-light-emitting material and lanthanide metalTwo kinds of Dy(III) MOFs of Dy-BTC and MxDy1-x-BTC (M = Gd3+, Zn2+, Ni2+, Mg2+) were successfully synthesized under similar solvothermal reaction conditions. The specific structures of these were analyzed by ...