In 1,2-dimethoxyethane; benzene byproducts: neohexene; under N2, drybox or Schlenk techniques; glass bomb with complex in DME and benzene, cooled (-196°C), degassed, 1-butene condensed into vessel, thawed, vessel wrapped with foil, soln. stirred (2.5 h), addn. of DME; evapn.; elem...
Ultrasonic relaxation spectra of the systems LiAsF added to the macrocyclic ethers 18-crown-6 (18C6) or 12-crown-4 (12C4), in molar ratio R approx. = 1, in the solvent 1,2-dimethoxyethane (DME) at t = 25°C, are reported. The concentration range covered was 0.05-0.25 M for 18C...
1, 2-Dimethoxyethane 1, 2-Dimethyl-3,6-epoxyperhydrophthalic anhydride 1, 2-Dimethyl-3-nitrobenzene 1, 2-Dimethyl-4-ethylbenzene 1, 2-Dimethyl-4-nitrobenzene 1, 2-Dinitrobenzol 1, 2-Diphenyl-3,5-dioxo-4-butylpyrazolidine 1, 2-Diphenylhydrazine 1, 2-Epoxy-3-(2-methylphenoxy) ...
(LiTFSI) and lithium nitrate (LiNO3) in the mixture of 1,3-dioxolane (DOL) and 1,2-dimethoxyethane (DME) as the electrolyte. The cell containing the aforementioned precursor was equipped with a lithium metal plate and carbon paper as the negative and positive electrode, respectively, and ...
With 1,2-dimethoxyethane; NaH-tBuONa-Ni(OAc)2 at 60℃; for 5h; A 6 % Chromat.B 90% With tris(2,2'-bipyridine)nickel(II) tetrafluoroborate; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide Electrolysis; A n/aB 35 % Chromat. 4-benzyl-1,4-dihydro-pyridine 110-86-1 pyr...
With hydrogen; Et4N In 1,2-dimethoxyethane at 100℃; under 38000 Torr; for 18h; Product distribution; further unsaturated compounds of different types; A 8%B 90% bis(3-phenylpropyl) selenide 103-65-1 Propylbenzene Conditions ConditionsYield With samarium diiodide In tetrahydrofuran at...
Interaction in Crystals: The Keyboard of Na⊕ Coordination Numbers in Its Carbazole Anion Salts Some local minima in the shallow potential of the system carbazole anion, sodium cation, and the ethers tetrahydrofuran, 1,2-dimethoxyethane,... H Bock,DCC N?Ther,Z Havlas,... - 《Angewandte Ch...
DME 1,2-dimethoxyethane DMF dimethyl formamide DMSO dimethyl sulfoxide cDNA complimentary DNA Dppp (R)-(+)-1,2-bis(diphenylphosphino)propane DuPhos (+)-1,2-bis((2S,5S)-2,5-diethylphospholano)benzene EDC N-(3-dimthylaminopropyl)-N′-ethylcarbodiimide EDCI N-(3-dimthylaminopropyl)-N′-ethy...
The vinyl ketones (4) of the structure ##STR185## are prepared by two general processes: (1) by reaction of vinyllithium (2 equivalents) with the appropriate carboxylic acid Q(CH2)pCR1R2CO2H (1 equivalent) in 1,2-dimethoxyethane according to the method described by J. C. Floyd in Tet...
In the first process step, organic solvents can be co-used which are preferably inert toward the reaction of compound (1) with compound (2). Examples of inert, organic solvents are toluene, xylene, octaneisomers, heptaneisomers, butyl acetate, 1,2-dimethoxyethane, tetrahydrofuran and cyclohexane...