The diruthenium(III) complex [Ru2O(O2CAr)2(MeCN)4(PPh3)2](ClO4)2 (1), on reaction with 1,2-diaminoethane (en) in MeOH at 25-degrees-C, undergoes nucleophilic attacks at the carbon of two facial MeCN ligands to form [(Ru2O)-O-III(O2CAr)2-{NH2CH2CH2N...
Metal-ligand coordinate bond energy terms have been calculated for ammonia complexes of: Li+, Mg+2, Co+2, Co+3, Ni+2, Cu+, Cu+2, Ag+, Zn+2, Cd+2, Hg+2; and for 1,2-diaminoethane complexes of: Mn+2, Fe+2, Co+2, Ni+2, Zn+2, Cd+2. Bond energy terms B(M+2 OH2)...
In the crystal structure of the title compound, [Ag2(N3)2(C2H8N2)], the Ag atoms of adjacent polymeric AgN3 chains are bridged by the 1,2-diaminoethane ligand to furnish a ribbon structure. The Ag atom shows trigonal planar coordination. The 1,2-diaminoethane ligand lies on an inversi...
This solid compound, also referred to as diphenyl-1,2-diaminoethane, is characterized by its two phenyl groups attached to an ethylenediamine backbone. It is commonly used as a ligand in coordination chemistry, where it forms complexes with metal ions. These complexes have been studied for their...
Reaction of 1,2-diaminoethane-N,N,N′,N′-tetra(N-methylacetamide), L, with potassium tetrachloroplatinate(II) in aqueous solution afforded the crystalline salt (2H+-L)[PtCl4] and the neutral platinum(IV) complex cis-Pt(LH−2)Cl2·2H2O. The crystal and molecular structure of the latte...
中文名称:1,2-二苯基乙二胺 英文名称:rel-(1R,2S)-1,2-Diphenyl-1,2-ethanediamine CAS No.:951-87-1 分子式:C14H16N2 分子量:212.290243148804 如需查看该化合物的详细结构式,mol文件,smile,InChi 请点击:1,2-二苯基乙二胺结构式 下载该化合物MOL文件:1,2-二苯基乙二胺MOL ...
2-diaminopropane is usually prepared by aminating a mixture of 2-amino-1-propanol and 1-amino-2-propanol, which is obtained from propylene oxide and ammonia. The process differs from corresponding processes for the production of diaminoethane in that the temperature in the catalytic amination is ...
Treatment of ruthenium (III) chloride hydrate with N,N′-dicarboxamido-N,N′-dicarboxymethyl-1,2-diaminoethane (1) (EDTA–diamide) in refluxing HCl solution followed by cooling afforded the crystalline complex NH4[Ru(EDTA–H)Cl] · 2H2O (2), the EDTA–H ligand and the +NH4 cation ...
BIS(DITHIOSQUARAMIDE) LIGANDS AND THEIR COMPLEXES WITH DIVALENT NICKEL: THERMOCHROMIC BEHAVIOUR AND UNANTICIPATED FORMATION OF 2:2 SPECIES Reaction of two equivalents of N-mono- or di-substituted 3-amino-4-(n-butoxy)-3-cyclobutene-1,2-diones with a 1,2-diaminoethane gave N-mono- or di-subst...
1,2-DiaminoethaneNitrogenous baseCopper(II) complexesNickel(II) complexesDithioleThione1,1-DithiolatoA series of divalent nickel and copper complexes and a series of mixed-ligand nickel(II) chelates have been prepared and characterized. The general formula of the complexes is [cation] 2[M(1,1-...