Energetically significant anti-parallel pi-stacking and unconventional anion-pi interactions in phenanthroline based Ni(II) and Cu(II) coordination compoun... Two new coordination compounds of Ni(II) and Cu(II), viz. [Ni(phen)(2)Cl(H2O)] 4-NO(2)bz center dot 3H(2)O (1) and [Cu(ph...
In this manuscript we report a high-level ab initio study of anion-pi interactions involving N9-methyl-adenine, N6-methyl-adenine, N9-methyl-hypoxanthine, a dimer of N9-methyl-adenine, and N9,N9'-trimethylene-bisadenine. DNA bases like adenine are electron-deficient arenes that are well suited...
R. Anion-π interactions in supramolecular architectures. Acc. Chem. Res. 2013, 46, 894-906.Chifotides HT, Dunbar KR (2013) Anion–pi interactions in supramolecular architectures. Acc Chem Res 46:894–906. : 10.1021/ar300251k View Article...
Reactions of bppn with AgX produce the grid-type structures [Ag4(bppn)4][X]4 (6-9), regardless of the anion present. In 6-9, pi-pi stacking interactions are maximized, whereas multiple and shorter (therefore stronger) anion-pi interactions between the anions and the tetrazine rings are ...
A reasonable explanation is that Anion- π interactions prevent the loss of X · from the [NO 2 -B15C5 + Cu + X] + ions. The presence of the electron-withdrawing NO 2 group causes the aromatic ring to be poor in electrons and thus its enhances its interactions with anions. For the ...
Combined Cation-pi and Anion-pi Interactions for Zwitterion RecognitionPerraud, ORobert, VGornitzka, HMartinez, ADutasta, J PPerraud O, Robert V, Gornitzka H, Martinez A, Dutasta J-P (2012) Combined cation–π and anion–π interactions for zwitterion recognition. Angew Chem Int Ed 51:...
a0,3 mm - mask for the glue. 0,3毫米-面具为胶浆。[translate] aentrr you entrr您[translate] aThermodynamics of Anion-pi Interactions in Aqueous Solution 阴离子pi互作用热力学在水溶液[translate]
In recent years, a number of experimental and theoretical studies have investigated the possibility of building anion-sensing receptors for their potential application in diverse areas as biology, medicine, and catalysis. Contrary to the expectation that the interactions are repulsive, theoretical investiga...
1. Anion-pi Interactions in Crystal Structures: Commonplace or Extraordinary? [J] . Hay BP, Custelcean R Crystal growth & design . 2009,第6期 机译:晶体结构中的阴离子-π相互作用:是平常的还是非凡的? 2. Molybdenum(VI) network polymers based on anion-pi interaction and hydrogen bonding: Sy...
Cation-pi and anion-pi interactionsIn this review, we analyze the interaction of ions with aromatic ringsFronteraQuioneroDeyàCation-pi and anion-pi interactions. Antonio Frontera,David Quinonero,Pere M. Deya. WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE . 2011...