Kanai, Asymmetric synthesis of tertiary alcohols and alpha-tertiary amines via Cu-catalyzed C-C bond formation to ketones and ketimines. Chem. Rev. 108, 2853- 2873 (2008). Medline doi:10.1021/cr078340rAsymmetric synthesis of tertiary alcohols and α-tertiary amines via Cu-catalyzed C - C ...
TERTIARY AND SECONDARY AMINES AS ALPHA-2 ANTAGONI
alpha-Tertiary aminesWe demonstrated a ruthenium-catalyzed regioselective allylic amination of tertiary allylic esters with various amines using [Cp*Ru(CH3CN)(3)][PF6]/5,5'-dimethyl-2,2'-bipyridine (5,'-diMe-2,2'-bpy) and related ruthenium catalytic systems, and successfully obtained a ...
amineshydroaminationsulfamatesAn efficient and mild trifluoromethanesulfonic acid-catalyzed hydroamination of unfunctionalized alkenes to afford alpha-tertiary amine derivatives at temperatures as low as room temperature is reported. 2,2,2-Trifluoroethyl sulfamate was found to be the optimal nitrogen source...
alkenesamineshydroaminationsulfamatesAn efficient and mild trifluoromethanesulfonic acidoi:info:doi/10.1002/adsc.201500646CaiNanjingZherenNanjingWangNanjingZhenNanjingChengNanjingXuNanjingSunNanjingHaoNanjingFeiNanjingJunNanjingAdvanced synthesis & catalysis
Alpha-cyclization of Tertiary-amines .4. Cyano-imidoyl Substituted Furans From Captodative Enamines and DibenzoylacetyleneSIMPLIFIED UNRESTRICTED HARTREE-FOCK APPROXIMATION (SUHFDIATOMIC MOLECULESELECTRONIC GROUND STATE CONFIGURATIONSTOTAL ENERGIES1ST IONIZATION POTENTIALSATOMIC CHARGES...
Alpha-cyclization of Tertiary-amines .3. Captodative Or Push-pull Enamines Form Pyrrolines, Pyrrolizidines and Their Ring Homologs With Dimethyl Acetylenedicarboxylate in a Highly Diastereoselective Reactionring closure reactionspyrrole derivativesfused pyrrole derivatives...
Novel salts of tertiary amines and alpha-substituted carboxylic acids have advantages as delayed action thermally activated catalyts such as in urethane and epoxy catalysis. Some salts of tertiary amines tend to dissociate reversibly when heated. However, the compounds of the present invention ...
alpha-Alltylation of tertiary amines by C(sp(3))-C(sp(3)) cross-coupling under redox neutral photocatalysisPhoto chemistryC-H alkylationVisible lightC(sp)(3)-C(sp)(3) C-H couplingTertiary amineDirect cc-alkylation of N-phenyl-tetrahydroisoquinoline with alkyl selenides of desired alkyl ...
MEYER MICHAEL D.DEBERNARDIS JOHN F.PRASAD RAJNANDANSIPPY KEVIN B.TIETJE KARIN R.WO1993012754A2 * Dec 14, 1992 Jul 8, 1993 Abbott Laboratories Tertiary and secondary amines as alpha-2 antagonists and serotonin uptake inhibitors