水汽转化反应描述了一氧化碳和水蒸气生成二氧化碳和氢气的反应(一氧化碳和氢气的混合物被称为水煤气):CO + H2O= CO2 + H2 The water gas shift reaction was discovered by Italian physicist Felice Fontana in 1780. It was not until much later that the industrial value of this reaction wa...
CO2 reverse water-gas shift reaction on mesoporous M-Ce O2 catalysts. DAI B C,ZHOU G L,GE S B,et al. The Canadian Journal of Chemical Engineering . 2017DAI B C,ZHOU G L,GE S B,et al. CO2 reverse water-gas shift reaction on mesoporous M-CeO2 catalysts[J]. The Canadian Journal ...
When the protein was expressed with liposomes, 6 mg/mL final concentration in the reaction mixture was used. A 25-mM amino acid mixture was used to provide enough volume for liposomes. See Supplemental Methods for details and Figure S1 of purification of NtAQP1 and NtPIP2;1. Liposome ...
CO2 solubility and solution speciation were simulated by nine equilibrium reactions. Two of the equilibrium constants were adjusted to match literature data. The rate of absorption was predicted by the theory of diffusion with fast chemical reaction. Piperazine at 24 mol% of the total amine ...
(insets in the top left corner are the different routes for generation of CO from CO2, in which * means catalyst). Full size image To demonstrate the proof-of-concept, this study explores the reduction reaction of CO2to CO using copper (Cu) as the catalyst. Cu is the only metal cataly...
In recent years, many studies focused on the foam behavior with CO2-soluble surfactants. However, it would be better if the mixing surfactants solution could increase the foam viscosities further and keep the considerable solubility in CO2 comparing with single CO2-soluble surfactant. In this paper...
while dry powder is utilized to put out such burning metals as magnesium and phosphorus. Halogenated hydrocarbons, commonly called halons, take the form of liquefiedgasor vaporizing liquids at room temperature; theyinhibitthe flamechain reaction. Steam is used to control fire in confined areas, whi...
In the present work, a series of ab initio molecular dynamics simulations have been carried out along with the metadynamics technique which reveals a stepwise mechanism: the reaction of a water molecule with CO2 yields HCO3− as an intermediate and a hydronium ion, whereas the protonation of ...
The CO2-to-C2H4 conversion in this alkali-cation-free six-APMA-MEA-cell stack was up to ~39%. After 1,000 h of operation, no GDE flooding was observed, which could be attributed to the increased reaction temperature (60 °C) allowing H2O accumulated in the GDEs to be discharged ...
Applications of homogeneous water-gas shift reaction. III. A further study of the hydrocarbonylation. A highly selective formation of diethyl ketone from e... The hydrocarbonylation of ethene with CO and H2O produces diethyl ketone with a high selectivity of 99±1%(propanal 1±1%); a Co2(CO...